Nanotechnology has been studied on environmental remediation processes to foster greater photocatalysts efficiency and reuse in wastewater. This study investigated the photocatalytic efficiency and viability of niobium pentoxide (NbO) nanoparticles decorated with magnetic ferrite (cobalt ferrite (CoFeO) or magnesium ferrite (MgFeO)) for atrazine photodegradation. Thus, the decorated NbO was synthesized by the polymeric precursor method, forming nanoparticles with sizes ranging from 25 to 50 nm. Nanocomposite elementary analyses showed a homogeneous distribution of elements on all particles surface. Efficient magnetic saturation was observed for pure CoFeO (53 emu g) and MgFeO (19 emu g) nanoparticles, promoting the magnetic removal of NbO:CoFeO and NbO:MgFeO nanocomposites. Photocatalytic assays showed 88% efficiency for atrazine photodegradation with all nanomaterials, which represented a 21% increase compared to photolysis in the 1st cycle. The magnetic nanocomposites when applied to a 5th cycle maintained the atrazine photodegradation activity. In this way, magnetic NbO-based nanocomposites decorated with ferrite nanoparticles showed an efficient photocatalytic response, in addition to posterior magnetic removal from the aqueous medium. Therefore, the evaluated magnetic NbO nanocomposites may be an alternative to enhance the wastewater removal process and foster the reuse in advanced oxidative processes.
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http://dx.doi.org/10.1007/s11356-020-11262-5 | DOI Listing |
Chemosphere
December 2024
Département des sciences de la Terre et de l'atmosphère, Université du Québec à Montréal, Montréal, QC, H2X 1Y4, Canada; Geotop Research Centre, Montréal, QC, H2X 3Y7, Canada. Electronic address:
Many processes can contribute to the attenuation of the frequently detected and toxic herbicides atrazine and metolachlor in surface water, including photodegradation. Multi-element compound-specific isotope analysis has the potential to decipher between these different degradation pathways as Cl is a promising tool for both pathway identification and a sensitive indicator of degradation for both atrazine and metolachlor. In this study, photodegradation experiments of atrazine and metolachlor were conducted under simulated sunlight in buffered solutions (direct photodegradation) and with nitrate (indirect photodegradation by OH radicals) to determine kinetics, transformation products and isotope fractionation for C, N and for the first time Cl.
View Article and Find Full Text PDFJ Environ Sci Health B
December 2024
VNU Key Laboratory of Advanced Material for Green Growth, Faculty of Chemistry, VNU University of Science, Thanh Xuan, Hanoi, Vietnam.
Frequent use of pesticides results in the release of large quantities of their residues in the environment, raising various concerns for humans and the ecosystem. This work introduces a simple and cost-effective method for removal atrazine pesticide residue (APR) from agricultural wastewater using Cu doped-ZnO photocatalyst (Cu-ZnO). The modification of ZnO with Cu significantly improved its optical and photoelectrochemical properties, with the band gap narrowing from 3.
View Article and Find Full Text PDFChemosphere
November 2024
Institute of Research and Development, Duy Tan University, Da Nang, Viet Nam; School of Engineering & Technology, Duy Tan University, Da Nang, Viet Nam. Electronic address:
Environ Sci Process Impacts
June 2024
Civil and Urban Engineering Department, Tandon School of Engineering, New York University, Brooklyn, New York 11201, USA.
Accurate quantum yields are crucial for modeling photochemical reactions in natural and engineered treatment systems. Quantum yields are usually determined using a single representative light source such as xenon lamps to mimic sunlight or UVC light for water treatment. However, photodegradation modeling can be improved by understanding the wavelength dependence of quantum yields and the potential errors introduced by the experimental setup.
View Article and Find Full Text PDFSci Rep
March 2024
Environmental Health Engineering, Khoy University of Medical Sciences, Khoy, West Azerbaijan, Iran.
Due to its widespread use in agriculture, atrazine has entered aquatic environments and thus poses potential risks to public health. Therefore, researchers have done many studies to remove it. Advanced reduction process (ARP) is an emerging technology for degrading organic contaminants from aqueous solutions.
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