We study the role of ionic correlations on the electroosmotic flow in planar double-slit channels, without salt. We propose an analytical theory, based on recent advances in the understanding of correlated systems. We compare the theory with mean-field results and validate it by means of dissipative particle dynamics simulations. Interestingly, for some surface separations, correlated systems exhibit a larger flow than predicted by mean-field. We conclude that the electroosmotic properties of a charged system can be used, in general, to infer and weight the importance of electrostatic correlations therein.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d0sm01523g | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Synergistic enhancement in ultra-trace thallium(I) removal using the titanium dioxide/biochar composite.
J Environ Manage
January 2025
Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, School of Environmental Science and Engineering, Guangzhou University, Guangzhou, 510006, China. Electronic address:
Thallium (Tl), recognized for its high toxicity, is subject to stringent international regulations regarding its permissible concentrations at ultra-trace levels. In this study, titanium dioxide (TiO) was integrated with potassium (K)-rich biochar to create TiO/biochar (TiO/BC) composites for synergistic enhancement in ultra-trace Tl(I) removal, focusing on achieving concentration below the rigorous local threshold of 0.1 μg/L for drinking water.
View Article and Find Full Text PDFThe nature of halogen bonding: insights from interacting quantum atoms and source function studies.
IUCrJ
March 2025
Department of Chemistry, Università degli Studi di Milano, via Golgi 19, 20133 Milano, Italy.
A detailed study of the X...
View Article and Find Full Text PDFInterfacial Adsorption Interactions of Dyes and Chitosan/Activated Carbon@Curcumin Derivatives in Single-Component and Binary Solutions.
Langmuir
January 2025
Hephaestus Laboratory, School of Chemistry, Faculty of Sciences, Democritus University of Thrace, GR-65404 Kavala, Greece.
The remediation of wastewaters contaminated with dyes (discharged mainly from industry) is very important for preserving environmental quality and human health. In this study, a new composite chitosan (CS)-based adsorbent combined with activated carbon (AC) and curcumin (Cur) (abbreviated hereafter as CS/AC@Cur) in three different ratios (12.5%, 25%, and 50%) was synthesized for the removal of anionic [reactive black 5 (RB5)] and cationic [methylene blue (MB)] dyes in single-component or binary systems.
View Article and Find Full Text PDFQuantum Molecular Dynamics Approach to Understanding Interactions in Betaine Chloride and Amino Acid Natural Deep Eutectic Solvents.
ACS Phys Chem Au
January 2025
Instituto de Ciência e Tecnologia, Universidade Federal de São Paulo, São José dos Campos, 12247-014 São Paulo, Brazil.
The unique properties and versatile applications of natural deep eutectic solvents (NaDES) have sparked significant interest in the field of green chemistry. Comprised of natural components that form liquids at room temperature through strong noncovalent electrostatic interaction, these solvents are cost-effective, nontoxic, and versatile. Betaine chloride-based NaDES, in particular, have shown promise in biocatalysis and sugar extraction due to their excellent properties.
View Article and Find Full Text PDFOptimized Synthesis and Stabilization of Superparamagnetic Iron Oxide Nanoparticles for Enhanced Biomolecule Adsorption.
ACS Omega
January 2025
Federal University of Espírito Santo, Av Marechal Campos 1468, Vitória, ES 29.040 090, Brazil.
Monodisperse and colloidally stable magnetic iron oxide nanoparticles have been developed for diverse biotechnology applications. Although promising for the adsorption of organic molecules, the low density of adsorption sites in these nanoparticles has been a significant challenge. In this study, an optimized factorial design with response surface methodology (RSM) was employed to produce small Superparamagnetic Iron Oxide Nanoparticles (SPIONs) stabilized with tetraethoxysilane (TEOS).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!