Aim: This study aims to evaluate the effect of three endodontic chelating agents (17% ethylenediamine tetra-acetic acid [EDTA], 1% peracetic acid [PAA], 0.2% Chitosan) on the push out bond strength of gutta percha with a new bioceramic sealer (BioRoot RCS).
Materials And Methods: Forty-eight single-rooted mandibular premolars were selected and decoronated to obtain standardized root length of 15 mm. The root canals were prepared up to #30 files (Hyflex CM) and copious irrigation was done with 3 ml of 5.25% of NaOCl. According to the final irrigation, specimens were divided into three groups: Group 1 ( = 16) 0.2% chitosan, Group 2 ( = 16) 17% EDTA, and Group 3 ( = 16) 1% PAA for 1 min. Samples from each group were obturated with bioceramic sealer and gutta percha and sealed with temporary filling material. Two horizontal slices of 2 mm was obtained from the middle third of each sample ( = 32). Push out bond strength and failure modes were assessed. Kruskal-Wallis test followed by Mann-Whitney analysis was used for push out analysis. Chi square test was used to compare the modes of failure. The statistical significance level was set at = 0.05.
Results: The highest push out bond strength was obtained with Group 1 (0.2% chitosan) followed by Group 3 (1% PAA). Group 2 (17% EDTA) showed least push out bond strength when compared to Group 1 (0.2% chitosan) and Group 3 (1% PAA). The mode of failure was mainly cohesive for all groups.
Conclusions: The highest push-out bond strength of BioRoot RCS was seen after treatment with 0.2% chitosan while the least was after EDTA treatment. 1% PAA treatment also favorably affected push-out bond strength of BioRoot RCS.
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http://dx.doi.org/10.4103/JCD.JCD_90_20 | DOI Listing |
Environ Sci Technol
January 2025
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, PR China.
Cadmium (Cd) isotopes have recently emerged as novel tracers of Cd sources and geochemical processes. Widespread clay minerals play a key role in Cd migration due to their strong adsorption capacity, but the mechanism of Cd isotope fractionation during adsorption onto clay minerals is poorly understood. Here, we experimentally investigated the adsorption mechanisms of Cd on montmorillonite (2:1) and kaolinite (1:1) by using extended X-ray absorption fine structure (EXAFS) spectroscopy.
View Article and Find Full Text PDFSci Rep
January 2025
State Key Laboratory of Structure Analysis, Optimization and CAE Software for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian, 116024, China.
The biocompatible autonomous self-healing hydrogels have great potential in biomedical applications. However, the fairly weak tensile strength of the hydrogels seriously hinders their application. Here, we introduced chitosan (CS) into the polyvinyl alcohol (PVA)-tannic acid (TA) hydrogel and investigated the effects of the CS content, as CS can not only form reversible H bonds with PVA and TA but also form reversible electrostatic interactions with TA.
View Article and Find Full Text PDFNat Commun
January 2025
Key Laboratory of Automobile Materials, Ministry of Education, Department of Materials Science and Engineering, Jilin University, 130022, Changchun, China.
Correlating the bond strength with the macro strength of metals is crucial for understanding mechanical properties and designing multi-principal-element alloys (MPEAs). Motivated by the role of grain boundaries in the strength of metals, we introduce a predictive model to determine the grain-boundary energies and strength of metals from the cohesive energy and atomic radius. This scheme originates from the d-band characteristics and broken-bond spirit of tight-binding models, and demonstrates that the repulsive/attractive effects play different roles in the variation of bond strength for different metals.
View Article and Find Full Text PDFJ Dent
January 2025
DDS, MS, PhD, Department of Dentistry, Federal University of Rio Grande do Norte, Natal, Brazil. Electronic address:
Objective: To evaluate the influence of different cleaning methods, surface treatments, and aging on the repair bond strength to a CAD/CAM glass-ceramic.
Materials And Methods: Forty-eight lithium disilicate CAD/CAM ceramic blocks were fabricated, sintered, and embedded in acrylic resin. After contamination with human saliva, they were divided according to the factors "Cleaning method" (Control-water/air spray, Air-particle abrasion with AlO, Ivoclean cleaning paste), "Surface treatment" (5% Hydrofluoric acid-HF + Silane, Monobond Etch & Prime-MEP), and "Aging" (thermocycling, no thermocycling).
Chemistry
January 2025
China University of Geosciences, Faculty of Materials Science and Chemistry, CHINA.
Pd cocatalysts show great potential for the photocatalytic production of H2O2. However, the catalytic efficiency of Pd cocatalyst is limited due to the strong adsorption of O2, which promotes O-O bond cleavage and thus reduces selectivity for the two-electron O2 reduction reaction. Considering that adjusting the electron density of Pd can predominately optimize Pd-Oads bond strength, in this work, electron-rich Pd sites are constructed by introducing Bi2Se3 middle layer between Pd cocatalysts and (010) facet of BiVO4 using an in-situ selenization strategy.
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