AI Article Synopsis
- The metal-organic framework Bi-BTC effectively catalyzes the creation of para-xylene from 2,5-dimethylfuran and acrylic acid with a high yield of 92%.
- This reaction occurs under mild conditions, specifically at 160°C and 10 bar, and features a low energy barrier of 47.3 kJ/mol.
- The process also shows flexibility for other furan derivatives, indicating it could be applied to substances like furan and 2-methylfuran.
Article Abstract
The heterogeneous metal-organic framework Bi-BTC successfully catalyzed the synthesis of para-xylene from bio-based 2,5-dimethylfuran and acrylic acid in a promising yield (92 %), under relatively mild conditions (160 °C, 10 bar), and with a low reaction-energy barrier (47.3 kJ mol ). The proposed reaction strategy also demonstrates a remarkable versatility for furan derivatives such as furan and 2-methylfuran.
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| http://dx.doi.org/10.1002/anie.202013061 | DOI Listing |
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