Owing to the diverse composition, adjustable performance, and synergistic effect among components, core-shell micro/nanoparticles have been widely applied in the field of tribology in recent years. The strong combination with the matrix and the good dispersion of reinforcing fillers in the composites could be achieved through the design of core-shell structural particles based on the reinforcing fillers. In addition, the performance of chemical mechanical polishing could be improved by optimizing the shell material coated on the abrasive surface. The physical and chemical state of the core-shell micro/nanoparticles played important effects on the friction and wear properties of materials. In this paper, the synthesis methods, the tribological applications (acted as solid/liquid lubricant additive, chemical mechanical polishing abrasives and basic units of lubricant matrix), and the functionary mechanisms of core-shell micro/nanoparticles were systematically reviewed, and the future development of core-shell micro/nanoparticles in tribology was also prospected.
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http://dx.doi.org/10.3390/ma13204590 | DOI Listing |
Int J Mol Sci
June 2024
Departament de Enginyeria Química, Universitat Politècnica de Catalunya, EEBE, Av. Eduard Maristany 10-14, 08019 Barcelona, Spain.
Surface modification of drug-loaded particles with polyethylene glycol (PEG) chains is a powerful tool that promotes better transport of therapeutic agents, provides stability, and avoids their detection by the immune system. In this study, we used a new approach to synthesize a biodegradable poly(ester amide) (PEA) and PEGylating surfactant. These were employed to fabricate micro/nanoparticles with a core-shell structure.
View Article and Find Full Text PDFACS Omega
March 2023
Department of Chemistry, Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 5290002, Israel.
In many industrial settings, films of polymers such as polypropylene (PP) and polyethylene terephthalate (PET) require surface treatment due to poor wettability and low surface energy. Here, a simple process is presented to prepare durable thin coatings composed of polystyrene (PS) core, PS/SiO core-shell, and hollow SiO micro/nanoparticles onto PP and PET films as a platform for various potential applications. Corona-treated films were coated with a monolayer of PS microparticles by dispersion polymerization of styrene in ethanol/2-methoxy ethanol with polyvinylpyrrolidone as stabilizer.
View Article and Find Full Text PDFSci Rep
November 2022
Iranian Center for Endodontic Research, Research Institute of Dental Sciences, Shahid Beheshti University of Medical Sciences, Tehran, 1983963113, Iran.
Nano-bio interactions are size-dependent. The present study investigates whether core-shell chitosan-alginate particle size governs biological activities as well as protein release profile. A coaxial electrospraying was used to fabricate bovine serum albumin (BSA)-loaded core-shell micro/nanoparticles and were fully characterized.
View Article and Find Full Text PDFMaterials (Basel)
October 2020
State Key Laboratory of Tribology, Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China.
Owing to the diverse composition, adjustable performance, and synergistic effect among components, core-shell micro/nanoparticles have been widely applied in the field of tribology in recent years. The strong combination with the matrix and the good dispersion of reinforcing fillers in the composites could be achieved through the design of core-shell structural particles based on the reinforcing fillers. In addition, the performance of chemical mechanical polishing could be improved by optimizing the shell material coated on the abrasive surface.
View Article and Find Full Text PDFChem Sci
January 2019
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province , Guizhou University, Guiyang , Guizhou 550025 , China . Email: ; Email:
Functional self-assemblies derived from noncovalent interactions such as lipid vesicles and DNA chiral double helices are a typical feature of natural life activity. Because of this phenomenon, a self-assembly approach for various functional organic particles is a desirable objective in supramolecular chemistry. Here, we report the discovery of enantiomeric conformers from a twisted macrocyclic host (), which was obtained from an achiral precursor by Schiff base reaction.
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