Nanoparticle coatings for stir bar sorptive extraction, synthesis, characterization and application.

During the last ten years, number of articles published on synthesis and applications of nano-particles (NPs) have been increased by a factor of 40. One of the most interesting applications of NPs is their using as high capacity, robust and highly selective coatings for stir bar sorption extraction (SBSE). Utilizing NPs greatly promoted applications of SBSE and has gained importance on green sample preparation. In this article, all available literature on nano-coatings as media for microextraction by stir bar is reviewed. This includes non-functionalized NPs (mostly, metallic/metallic oxide and graphene based), functionalized coatings, and decorated coatings (both mono- and multifunctional). Various applications, advantages and disadvantages of each nano-coated prepared stir bar are discussed in detail along with critical evaluation of currently available methods.