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Filename: controllers/Detail.php
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The electrolysis of water is popular both as lab work and as a demonstration. In this activity, the electrolysis of water in the presence of a pH indicator is used to produce text and symbols. This report describes the design of an environmentally friendly setup of a writing board utilizing the electrolysis of water in a hydrogel environment. The activity can be performed by only using chemicals and materials that are easily accessible to everyone, with no special permit needed. The writing board has been developed mainly as an outreach activity for our faculty and has been assessed during visits from upper secondary school students.
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http://dx.doi.org/10.1021/acs.jchemed.0c00440 | DOI Listing |
J Colloid Interface Sci
December 2024
Northwest Institute for Non-ferrous Metal Research, Xi'an 710016, China; School of Materials Science & Engineering, Xi'an University of Technology, Xi'an 710048, China. Electronic address:
High-entropy alloy (HEA) nanomaterials have emerged as promising candidates as oxygen evolution reaction (OER) electrocatalyst to overcome the existing issues of the sluggish reaction kinetics and poor stability. In this study, IrRuCoCuNi HEA three-dimensional-nanoframeworks (3DNF) are prepared using a scalable approach-the spray-drying technique combined with thermal decomposition reduction (SD-TDR). The optimized catalyst, IrRuCoCuNi, demonstrates superior OER performance, with an overpotential of 264 mV at 10 mA cm and a Tafel slope of 47 mV dec, considerably surpassing the catalytic activity of commercial IrO.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
Guangxi Key Laboratory of Low Carbon Energy Materials, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, China. Electronic address:
Developing an innovative metal-phosphorus heterostructure as an excellent electrocatalyst for hydrogen evolution reaction (HER) is crucial for achieving large-scale water electrolysis, although it remains challenging. Herein, we introduce a pioneering strategy entailing the coordination of two metal phosphides in a catalytic structure by employing a wide variety of catalytically active species and regulating the electronic structure. Our method involves an extraordinary heterostructure construction with nickel phosphide and molybdenum phosphide formed on nickel foam (NiP-MoP@NF) through a controlled-solvent thermal and low-temperature phosphorization strategy.
View Article and Find Full Text PDFNano Lett
December 2024
Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, P. R. China.
Developing highly efficient non-iridium-based active sites for acidic water splitting is still a huge challenge. Herein, unique Ru-B-Cr moieties have been constructed in RuO nanofibers (NFs) to activate Ru sites for water electrolysis, which overcomes the bottleneck of RuO-based catalysts usually possessing low activity for the hydrogen evolution reaction (HER) and poor stability for the oxygen evolution reaction (OER). The fabricated Cr, B-doped RuO NFs exhibit low overpotentials of 205 and 379 mV for acidic HER and OER at 1 A cm with outstanding stability lasting 1000 and 188 h, respectively.
View Article and Find Full Text PDFLangmuir
December 2024
College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, China.
The active site density, intrinsic activity, and supporting substrate of cobalt phosphide catalysts are vital to their performance in alkaline water electrolysis. In this work, a CoP/CoP loaded on cellulose nanofiber-derived carbon aerogels (CP/CCAs) bifunctional electrocatalyst with a three-dimensional network and heterostructure is illustrated through sequential facile hydrothermal, freeze-drying, and phosphorylation processes. The three-dimensional network of carbon aerogels derived from cellulose nanofibers reveals a specific surface area of 183.
View Article and Find Full Text PDFChem Sci
December 2024
Jiangsu Key Laboratory of New Power Batteries, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, School of Chemistry and Materials Science, Nanjing Normal University Nanjing 210023 China
Hydrazine-assisted water splitting is a promising strategy for energy-efficient hydrogen production, yet challenges remain in developing effective catalysts that can concurrently catalyze both the hydrogen evolution reaction (HER) and hydrazine oxidation reaction (HzOR) in acidic media. Herein, we report an effective bifunctional catalyst consisting of Rh clusters anchored on CoO branched nanosheets (Rh-CoO BNSs) synthesized an innovative arginine-induced strategy. The Rh-CoO BNSs exhibit unique Rh-O-Co interfacial sites that facilitate charge redistribution between Rh clusters and the CoO substrate, thereby optimizing their valence electronic structures.
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