Because of their unique three-dimensional cellular structure and intrinsic properties, polyimide foam materials have bright prospects for development in multiple functional equipment, which arouses extensive concern. In this Spotlight on Applications, several typical fabrication methods of polyimide foams and the related synthesis mechanism have been systematically described. The advantages and disadvantages of the preparation methods have been compared with each other. Representative functions and the corresponding mechanism models have been concluded, which involve thermal, mechanical, sensing, electromagnetic, environmental, and electrical fields. In the end, the severe tasks and challenges of polyimide foam materials have been summarized, and their promising future development is worth expecting.
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http://dx.doi.org/10.1021/acsami.0c15771 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Advanced Metallic Materials of Jiangsu Province, School of Materials Science and Engineering, Southeast University, Nanjing 211189, P. R. China.
Gradient structures are effective for microwave absorbing but suffer from inadequate lightweight and poor flexibility, making them fall behind the comprehensive requirements of electromagnetic protection. Herein, we propose a hierarchical gradient structure by integration with porous and sandwich structures. Specifically, polyimide (PI) foams are used as a robust and flexible skeleton, in which the foam cell walls are sandwiched by TiCT, ZnO, and ZrO atomic layers in sequence.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
School of Materials Science and Engineering, Xi'an Polytechnic University, Xi'an 710048, China.
The application of traditional isocyanate-based polyimide (PI) foams is highly hindered due to limited flame retardancy, poor mechanical properties, and relatively single functionality. Herein, we propose an effective method to fabricate dual cross-linked polyimide/bismaleimide (PI-BMI) foams with outstanding heat resistance and enhanced mechanical properties by incorporating bis(3-ethyl-5-methyl-4-maleimidophenyl)methane (ME-BMI) as the interpenetrating network. The results show that the prepared PI-BMI composite foams exhibit enhanced mechanical properties with lightweight characteristics (23-80 kg·m).
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2024
Research Center for GREEN Materials and Advanced Processing, Yamagata University, Yonezawa, Yamagata 992-8510, Japan.
This study explores the adhesive properties of copolymers comprising glycidyl methacrylate (GMA) and 3-(trimethoxysilyl)propyl methacrylate (MPTMS), focusing on their suitability for adhesive applications. Peel resistance measurements revealed a substantial impact of the GMA/MPTMS ratio on adhesion capabilities, identifying an optimal ratio of 30/70 for copolymerization with -butyl acrylate (BA) to improve foaming performance. BA, a foaming monomer activated by a photoacid generator and heat, enhances the copolymerized adhesive's adhesion strength and foamability for postuse delamination.
View Article and Find Full Text PDFMacromol Rapid Commun
November 2023
The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute, Sichuan University, Chengdu, 610065, China.
Lightweight polyimide foams (PIFs) with exceptional thermal resistance and compressive properties are fabricated by heating polyester ammonium salts (PEASs) which are prepared by copolymerizing 4, 4'-diaminobenzanilide (DABA), 4, 4'-diaminodiphenyl methane (MDA) and 3, 3', 4, 4'-benzophenone tetracarboxylic dianhydride (BTDA). Hydrogen bonds are formed between CONH and CO in the PI chains due to the addition of DABA and the melt viscosity of PEAS precursors increase with increasing content of DABA, which is advantageous to bind the foaming gases for cell expansion. The expansion ratio of PEAS precursors is increased from 633% to 1133% when the molar ratio of MDA/DABA is changed from 10:0 to 6:4.
View Article and Find Full Text PDFPolymers (Basel)
June 2023
School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xi'an 710072, China.
Polyimide foam (PIF) is a rising star in high-end applications such as aerospace thermal insulation and military sound absorption. However, the basic rule on molecular backbone design and uniform pore formation of PIF still need to be explored. In this work, polyester ammonium salt (PEAS) precursor powders are synthesized between alcoholysis ester of 3, 3', 4, 4'-benzophenone tetracarboxylic dianhydride (BTDE) and aromatic diamines with different chain flexibility and conformation symmetry.
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