Probing the inversion kinetics of a molecular helix is inherently a challenging task. We demonstrate herein that a fast-rotating pentiptycene component could function as an external NMR probe to afford the kinetic information on the inversion of a neighboring helical -stilbene unit.
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| http://dx.doi.org/10.1021/acs.orglett.0c02993 | DOI Listing |
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