A variety of metal organic frameworks (MOFs) were synthesized and evaluated for their iodine adsorption capacity. Out of the MOFs tested, ZIF-8 showed the most promising result with an iodine vapor uptake of 876.6 mg/g. ZIF-8 was then incorporated into a polymer, polyethersulfone (PES), at different proportions to prepare mixed matrix membranes (MMMs), which were then used to perform further iodine adsorption experiments. With a mixing ratio of 40 wt % of ZIF-8, the iodine adsorption capacity reached 1387.6 mg/g, wherein an astounding 60% improvement in adsorption was seen with the MMMs prepared compared to the original ZIF-8 powder.
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http://dx.doi.org/10.3390/polym12102309 | DOI Listing |
J Am Chem Soc
December 2024
School of Materials Science and Engineering, Peking University, Beijing 100871, P. R. China.
Potassium-iodine batteries show great promise as alternatives for next-generation battery technology, owing to their high power density and environmental sustainability. Nevertheless, they suffer from polyiodide dissolution and the multistep electrode fabrication process, which leads to severe performance degradation and limitations in mass-market adoption. Herein, we report a simple "solution-adsorption" strategy for scale-up production of TiC(OH)-wrapped carbon nanotube paper (CNP), as an economic host for strengthening the iodine encapsulation.
View Article and Find Full Text PDFChemistry
December 2024
Indian Institute of Technology Guwahati, Dept. of Chemistrty, North Guwahati, 781039, Guwahati, INDIA.
Bromine is a significant environmental threat due to its corrosive nature and contribution to ozone layer depletion. It often coexists with iodine and forms interhalogen complexes (IBr), which require an effective and selective bromine adsorption strategy. Leveraging the electrophilic nature of bromine, we designed an electron-rich thiophene-based porous organic polymer (POF-2).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Lanzhou University, College of chemistry and chemical engineering, Lanzhou, CHINA.
Imperfections in metal halide perovskites, such as those induced by light exposure or thermal stress, compromise device performance and stability. A key challenge is immobilizing volatile iodine produced by iodide oxidation and regenerating impurities like elemental lead and iodine. Here, we address this by integrating a redox-active supramolecular assembly of nickel octaethylporphyrin into perovskite film, functioning as both an immobilizer and redox shuttle.
View Article and Find Full Text PDFChem Asian J
December 2024
shandong university, chemistry, Shanda nanlu No.27, JInan, Shandong, jinan, CHINA.
The rapid advancement of industrial production has led to an increase in water pollutants, posing a significant threat to public health. With the deepening of research on pollutant adsorbents. The application of silsesquioxane-based cross-linked polymer networks in water pollution treatment has gradually attracted people's attention.
View Article and Find Full Text PDFInorg Chem
December 2024
Laboratory of Nuclear Energy Chemistry, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China.
Cage-based MOFs, with their customizable chemical environments and precisely controllable nanospaces, show great potential for the selective adsorption of guest molecules with specific structures. In this work, we have constructed a novel cage-based MOF [(CH)NH][(UO)(TMTTA)]·11.5DMF·2HO (IHEP-51), utilizing a triazine derivative poly(carboxylic acid), 4,4',4″-(((1,3,5-triazine-2,4,6-triyl)tris(((4-carboxycyclohexyl)methyl)azanediyl))tris(methylene))tribenzoic acid (HTMTTA), as an organic ligand and uranyl as a metal node.
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