A new process of NO removal from flue gas, using an integrated system of oxidation-absorption-biological reduction (OABR), is introduced. The experimental results show that increasing the NO oxidation ratio in flue gas can effectively improve the NO removal efficiency of the OABR system. The NO removal efficiency could reach 98.8% with 0.02 M NaHCO as the chemical absorbent and under the condition of the optimal NO oxidation ratio of 50%. During stable operation, the OABR system could maintain a high NO removal efficiency (above 94%) under the following conditions: 1-8 vol% (10-8 × 10 ppmv) O, 200-800 ppmv NO, 0.5-1.5 L/min gas flow rate and 100-800 ppmv SO. The nitrogen equilibrium results showed that about 59% of the nitrogen in the inlet NO were transformed to N through microbial denitrification, 37% of the nitrogen were converted to biological nitrogen for microbial growth, and only 1.1% of the nitrogen remained in the liquid phase. This new approach has an excellent NO removal performance and great potential for industrial application.
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http://dx.doi.org/10.1016/j.jhazmat.2020.124109 | DOI Listing |
Inorg Chem
January 2025
Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin 300071, China.
The fixation of carbon dioxide (CO) directly from flue gas into valuable chemicals like 2-oxazolidinones is of great significance for economic and environmental benefits, which is typically catalyzed by noble-metal catalysts and under harsh conditions. Herein, a novel 2-fold interpenetrated framework {[Co(μ-O)(TCA)(HDPTA)]·2HO·2DMF} [Co(II)-based metal-organic framework ()] containing [Co] clusters and highly dense amino groups (-NH) dispersed in the channel was prepared, exhibiting high solvent/pH stability and CO adsorption capacity (24.9 cm·g).
View Article and Find Full Text PDFFEBS J
January 2025
'The Protein Factory 2.0', Dipartimento di Biotecnologie e Scienze della Vita, Università degli Studi dell'Insubria, Varese, Italy.
The sequestration of carbon dioxide using carbonic anhydrase (CA) is one of the most effective methods for mitigating global warming. The burning of fossil fuels releases large quantities of flue gas; because of its high temperature and of the alkaline conditions required for CaCO precipitation in the mineralization process, thermo-alkali-stable CAs are needed. In this context, Manyumwa et al.
View Article and Find Full Text PDFChem Sci
January 2025
J. Mike Walker '66 Department of Mechanical Engineering, Texas A&M University College Station TX 77843 USA
This perspective work examines the current advancements in integrated CO capture and electrochemical conversion technologies, comparing the emerging methods of (1) electrochemical reactive capture (eRCC) though amine- and (bi)carbonate-mediated processes and (2) direct (flue gas) adsorptive capture and conversion (ACC) with the conventional approach of sequential carbon capture and conversion (SCCC). We initially identified and discussed a range of cell-level technological bottlenecks inherent to eRCC and ACC including, but not limited to, mass transport limitations of reactive species, limitation of dimerization, impurity effects, inadequate generation of CO to sustain industrially relevant current densities, and catalyst instabilities with respect to some eRCC electrolytes, amongst others. We followed this with stepwise perspectives on whether these are considered intrinsic challenges of the technologies - otherwise recommendations were disclosed where appropriate.
View Article and Find Full Text PDFACS Omega
January 2025
College of Safety Science & Engineering, Liaoning Technical University, Huludao, Liaoning 125105, China.
The objective of this study was to evaluate the effect of injecting flue gas (CO, N, and O) originating from coal-fired power plants into a coal seam on CH extraction and CO geological storage. To this end, a multifield thermal-fluid-solid-coupled mathematical model of flue gas injection extraction was established. The results showed that with the increase in time increase, the volume concentration of CH decreased, but the CO, N, and O increased.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Chemical Engineering, University of Almería, Carretera de Sacramento s/n 04120 La Cañada de San Urbano, Almería, Spain.
This work studies the influence of flue gas composition, its moisture and ash content, on the efficiency of a CO adsorption/desorption process to capture the CO from flue gases along with its subsequent reuse in greenhouse CO enrichment (Patent ES2514090). The influence of the inlet flow rate, moisture, and ash content were analysed. The experimental conditions were based on those that are achievable under real operating conditions, namely an inlet flow rate from 1.
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