The State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai, 200050, China.
Published: November 2020
AI Article Synopsis
Article Abstract
Atomically dispersed catalysts, with maximized atom utilization of expensive metal components and relatively stable ligand structures, offer high reactivity and selectivity. However, the formation of atomic-scale metals without aggregation remains a formidable challenge due to thermodynamic stabilization driving forces. Here, a top-down process is presented that starts from iron nanoparticles, using dual-metal interbonds (RhFe bonding) as a chemical facilitator to spontaneously convert Fe nanoparticles to single atoms at low temperatures. The presence of RhFe bonding between adjacent Fe and Rh single atoms contributes to the thermodynamic stability, which facilitates the stripping of a single Fe atom from the Fe nanoparticles, leading to the stabilized single atom. The dual single-atom Rh-Fe catalyst renders excellent electrocatalytic performance for the hydrogen evolution reaction in an acidic electrolyte. This discovery of dual-metal interbonding as a chemical facilitator paves a novel route for atomic dispersion of chemical metals and the design of efficient catalysts at the atomic scale.
Laminating a free-standing carbon electrode film onto perovskite film is a promising method for fabricating HTM (hole transport material)-free carbon electrode perovskite solar cells (c-PSCs), offering more flexibility by decoupling the processes of carbon electrode and perovskite layer formation. However, the power conversion efficiency (PCE) of laminated HTM-free c-PSCs (<16.5%) remains lower compared to c-PSCs with printed carbon pastes (>20%), primarily due to poor interfacial contact between the perovskite and carbon layers.
Synthetic photobiocatalysts are promising catalysts for valuable chemical transformations by harnessing solar energy inspired by natural photosynthesis. However, the synergistic integration of all of the components for efficient light harvesting, cascade electron transfer, and efficient biocatalytic reactions presents a formidable challenge. In particular, replicating intricate multiscale hierarchical assembly and functional segregation involved in natural photosystems, such as photosystems I and II, remains particularly demanding within artificial structures.
Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China.
The rational design of molecules with the desired functionality presents a significant challenge in chemistry. Moreover, it is worth noting that making chemicals safe and sustainable is crucial to bringing them to the market. To address this, we propose a novel deep learning framework developed explicitly for inverse design of molecules with both functionality and biocompatibility.
Background: Discovering insecticidal proteins with high activity and strict insect specificity and applying them to the biological control of insect pests is of great significance. Oral LqhIT2 has insecticidal activity, which most other insecticidal neurotoxin proteins do not have, but the large-scale preparation of the toxin is difficult and one of the obstacles to determining its anti-insect potential for biological control.
Results: In this study, the expression level of recombinant LqhIT2 (rLqhIT2) in Pichia pastoris was as high as 1.
The World Health Organization (WHO) reports 684,000 deaths/year due to slips and falls (SFs), with ∼38 million people requiring medical attention per annum. In particular, SFs on ice surfaces account for 45% of all SF incidents, costing over $100 billion globally in healthcare, intensive care, and insurance expenses. Current antislip solutions focus on hydrophobicity to repel interfacial fluids, aiming to maintain solid-to-solid contact.
