We show that the entropy production rate bounds the rate at which physical processes can be performed in stochastic systems far from equilibrium. In particular, we prove the fundamental tradeoff ⟨S[over ˙]_{e}⟩T≥k_{B} between the entropy flow ⟨S[over ˙]_{e}⟩ into the reservoirs and the mean time T to complete any process whose time-reversed is exponentially rarer. This dissipation-time uncertainty relation is a novel form of speed limit: the smaller the dissipation, the larger the time to perform a process.
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http://dx.doi.org/10.1103/PhysRevLett.125.120604 | DOI Listing |
Chemosphere
September 2023
Technical University of Berlin, Chair of Water Quality Control, KF4, Str. des 17. Juni 135, 10623, Berlin, Germany.
Managed aquifer recharge systems for drinking water reclamation are challenged by trace organic chemicals (TOrCs) since some of them are poorly retained. Although a lot of research has been done to investigate biological transformation of TOrCs in sand filter systems, there are still uncertainties to predict the removal. A laboratory column system with two different filter sands was set up to test TOrC transformation, the influence of low oxygen concentrations as well as the adaptation and influence of spiked TOrC influent concentrations.
View Article and Find Full Text PDFPhys Rev Lett
February 2022
School of Physics, Zhengzhou University, Zhengzhou 450001, China.
Dissipation is vital to any cyclic process in realistic systems. Recent research focus on nonequilibrium processes in stochastic systems has revealed a fundamental trade-off, called dissipation-time uncertainty relation, that entropy production rate associated with dissipation bounds the evolution pace of physical processes [Phys. Rev.
View Article and Find Full Text PDFPhys Rev Lett
September 2020
Complex Systems and Statistical Mechanics, Department of Physics and Materials Science, University of Luxembourg, L-1511 Luxembourg, Luxembourg.
We show that the entropy production rate bounds the rate at which physical processes can be performed in stochastic systems far from equilibrium. In particular, we prove the fundamental tradeoff ⟨S[over ˙]_{e}⟩T≥k_{B} between the entropy flow ⟨S[over ˙]_{e}⟩ into the reservoirs and the mean time T to complete any process whose time-reversed is exponentially rarer. This dissipation-time uncertainty relation is a novel form of speed limit: the smaller the dissipation, the larger the time to perform a process.
View Article and Find Full Text PDFEntropy (Basel)
July 2019
Department of Mechanical and Industrial Engineering, Università di Brescia, via Branze 38, 25123 Brescia, Italy.
In the domain of nondissipative unitary Hamiltonian dynamics, the well-known Mandelstam-Tamm-Messiah time-energy uncertainty relation τ F Δ H ≥ ℏ / 2 provides a general lower bound to the characteristic time τ F = Δ F / | d 〈 F 〉 / d t | with which the mean value of a generic quantum observable can change with respect to the width Δ F of its uncertainty distribution (square root of fluctuations). A useful practical consequence is that in unitary dynamics the states with longer lifetimes are those with smaller energy uncertainty Δ H (square root of energy fluctuations). Here we show that when unitary evolution is complemented with a steepest-entropy-ascent model of dissipation, the resulting nonlinear master equation entails that these lower bounds get modified and depend also on the entropy uncertainty Δ S (square root of entropy fluctuations).
View Article and Find Full Text PDFJ Environ Qual
December 2008
Geological Survey of Denmark and Greenland, GEUS, Øster Voldgade 10, DK-1350 Copenhagen K, Denmark.
Dissipation time is a key parameter when studying and modeling the environmental fate of pesticides. This study was conducted to characterize the variability of pesticide disappearance in soil and to identify possible controlling parameters related to intrinsic soil properties and microbiology. Multivariate data analysis was used to study spatial variability in three horizons from 24 sandy soil profiles.
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