Bisphenol A is a synthetic compound widely used in industry, in the production of polycarbonate, epoxy resins, and thermal paper, among others. Its annual production is estimated at millions of tons per year, demonstrating its importance. Despite its wide application in various everyday products, once in the environment (due to its disposal or leaching), it has high toxicity to humans and animal life, and this problem has been well known for years. Given this problem, many researchers seek alternatives for its monitoring in matrices such as natural water, waste, food, and biological matrices. For this, new advanced materials have been developed, characterized, and applied in creative ways for the preparation of samples for the determination of bisphenol A. This article aims to present some of these important and recent applications, describing the use of molecularly imprinted polymers, metal and covalent organic frameworks, ionic liquids and magnetic ionic liquids, and deep eutectic solvents as creative solutions in sample preparation for the long-standing problem of bisphenol A determination.
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http://dx.doi.org/10.1002/jssc.202000923 | DOI Listing |
Foods
January 2025
School of Biotechnology, Jiangnan University, Wuxi 214000, China.
The use of nanozymes for electrochemical detection in the food industry is an intriguing area of research. In this study, we synthesized a laccase mimicking the MnO@CeO nanozyme using a simple hydrothermal method, which was characterized by modern analytical methods, such as transmission electron microscope (TEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDX), etc. We found that the addition of MnO significantly increased the laccase-like activity by 300% compared to CeO nanorods.
View Article and Find Full Text PDFFoods
December 2024
Departamento de Química, Área de Química Analítica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofísico Francisco Sánchez s/n, 38206 San Cristóbal de La Laguna, Tenerife, Spain.
In this work, two novel (-)-menthol-based hydrophobic natural eutectic solvents with vanillin and cinnamic acid were prepared and applied as extraction solvents. In this regard, 12 endocrine disruptors, including phenol, 2,4-dimethylphenol, 2,3,6-trimethylphenol, 4--butylphenol, 4--butylphenol, 4--amylphenol, 4--hexylphenol, 4--octylphenol, 4--heptylphenol, 4--octylphenol, and 4--nonylphenol and bisphenol A, were studied in a green tea drink. A temperature-controlled liquid-liquid microextraction was used as the extraction method, and nano-liquid chromatography-ultraviolet detection was used as the separation and determination system.
View Article and Find Full Text PDFMolecules
January 2025
Department of Environmental Chemistry and Bioanalytics, Gagarina 7, Faculty of Chemistry, Nicolaus Copernicus University, 87-100 Torun, Poland.
Bisphenols may negatively impact human health. In this study, we propose the use of HPLC-FLD for the simultaneous determination of bisphenols in pericardial fluid samples collected from patients with coronary artery disease undergoing coronary artery bypass surgery. For sample preparation, a fast, simple, and "green" DLLME method was used, achieving mean recovery values in the range of 62%-98% with relative standard deviations between 2% and 6% for all analytes.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
School of Ecology and Environmental Science, Yunnan University, Kunming 650504, China.
Safer chemical alternatives to bisphenol (BP) have been a major pursuit of modern green chemistry and toxicology. Using a chemical similarity-based approach, it is difficult to identify minor structural differences that contribute to the significant changes of toxicity. Here, we used omics and computational toxicology to identify chemical features associated with BP analogue-induced embryonic toxicity, offering valuable insights to inform the design of safer chemical alternatives.
View Article and Find Full Text PDFJ Contemp Dent Pract
September 2024
Department of Academic, Faculty of Dentistry, Universidad Nacional Federico Villarreal, Lima, Peru, ORCID: https://orcid.org/0000-0002-0594-5834.
Objective: To evaluate the shear strength of adhesives based on the type of solvent (ethanol and acetone), aged and light-cured using light-emitting diode (LED) units with different wavelengths. Polywave and monowave LED units were employed for this study.
Materials And Methods: Ninety bovine tooth samples were analyzed using OptiBond Universal adhesive (acetone) and single bond universal adhesive (ethanol).
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