The assembly of two different building blocks, [{Au(C F ) }{PbCl(terpy)}] (terpy=2,2':6':2''-terpyridine) and [{Au(C F ) } {Pb(terpy)}] , acting as terminal or central pieces, respectively, gives rise to a decanuclear complex built via metallophilic and π-stacking interactions in which the number of Au ⋅⋅⋅Au and Au ⋅⋅⋅Pb contacts is finely controlled.
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| http://dx.doi.org/10.1002/anie.202010095 | DOI Listing |
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