Occurrence of dioxin-like POPs in soils from urban green space in a metropolis, North China: implication to human exposure.

Urban green space is a special space for urban life and natural contact and has an important impact on human health. However, little information is available on dioxin-like persistent organic pollutants (POPs) in the soils from the specific areas. We measured the concentrations of polychlorinated naphthalenes (PCNs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), and polychlorinated biphenyls (PCBs) in the soils from urban green space in a metropolis, North China, and found total concentrations of PCDD/Fs, PCBs, and PCNs in the range of 11.5-91.4, 14.7-444, and 82.5-848 pg/g, respectively. It was worth to notice that the concentrations of PCDD/Fs in public park soil from urban center were significantly higher than those in the road greenbelts and resident lawns (Kruskal-Wallis test, p = 0.004). The source analysis indicated that sewage sludge from wastewater treatment plants were important sources of PCNs and PCDD/Fs in urban green land soils, and atmospheric deposition from municipal solid waste incinerator (MSWI) also play an important role in PCDD/F sources. The rough exposure risk evaluation showed that the residents were at a safe level with the daily doses being 0.172-3.144 fg/kg BW/day for children and 0.022-0.406 fg/kg BW/day for adult. Due to the complex and variable sources of PCDD/Fs in urban areas, dioxin-like POPs in urban green land should be given more attention to weaken human exposure.