We study the Brownian motion of ellipsoidal particles lying on an agitated granular bath composed of magnetic particles. We quantify the mobility of different floating ellipsoidal particles using the mean-square displacement and the mean-square angular displacement, and relate the diffusion coefficients to the bath particle motion. In terms of the particle major radius R, we find the translational diffusion coefficient scales roughly as 1/R^{2} and the rotational diffusion coefficient scales as roughly 1/R^{4}; this is consistent with the assumption that diffusion arises from random kicks of the bath particles underneath the floating particle. By varying the magnetic forcing, the bath particles' diffusivity changes by a factor of ten; over this range, the translational and rotational diffusion of the floating particles change by a factor of 50. However, the ratio of the two diffusion constants for the floating particles is forcing-independent. Unusual aspects of the floating particle motion include non-Gaussian statistics for their displacements.
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http://dx.doi.org/10.1103/PhysRevE.102.022902 | DOI Listing |
ACS Nano
January 2025
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.
Block copolymers (BCPs) can form nanoparticles having different morphologies that can be used as photonic nanocrystals and are a platform for drug delivery, sensors, and catalysis. In particular, BCP nanoparticles having disk-like shape have been recently discovered. Such nanodisks can be used as the next-generation antitumor drug delivery carriers; however, the applicability of the existing nanodisks is limited due to their poor or unknown ability to respond to external stimuli.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Physics and Astronomy, The University of Edinburgh, Peter Guthrie Tait Road, Edinburgh EH9 3FD, UK; Department of Physics, University of Gothenburg, SE-41296 Gothenburg, Sweden; University of Münster, Institute of Physical Chemistry, Corrensstr. 28/30, 48149 Münster, Germany. Electronic address:
Hypothesis: Ellipsoidal particles confined at liquid interfaces exhibit complex self-assembly due to quadrupolar capillary interactions, favouring either tip-to-tip or side-to-side configurations. However, predicting and controlling which structure forms remains challenging. We hypothesize that introducing a polymer-based soft shell around the particles will modulate these capillary interactions, providing a means to tune the preferred self-assembly configuration based on particle geometry and shell properties.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2024
Institute of Physical Chemistry, Rheinisch-Westfälische Technische Hochschule Aachen University, Aachen 52074, Germany.
The adsorption of ellipsoidal colloidal particles on liquid interfaces induces interfacial deformation, resulting in anisotropic interface-mediated interactions and the formation of superstructures. Soft prolate-shaped microgels at the air-water interface offer an ideal model for studying spontaneous capillary-driven self-assembly due to their tunable aspect ratio, controlled functionality, and softness. These microgels consist of a polystyrene core surrounded by a cross-linked, fluorescently labeled poly([Formula: see text]-isopropylmethylacrylamide) shell.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Key Laboratory of Highway Engineering of Ministry of Education, Changsha University of Science & Technology, Changsha 410114, China.
The morphology of an individual particulate refers to its shape characteristics and size properties, which both play important roles for granular matter in physics, mechanics, chemistry, and biology. In this study, ellipsoidality is defined as a 3D shape index for evaluating particle roundness, and an explicit calculation method is applied. The dependences of 3D shape characteristics (aspect ratios, sphericity, and ellipsoidal degree) on particle size (ranges from 0.
View Article and Find Full Text PDFNanomaterials (Basel)
November 2024
Institute for Drug Research, The School of Pharmacy, Faculty of Medicine, The Hebrew University of Jerusalem, Jerusalem 9112001, Israel.
Mechanically driven cellular preference for drug carriers can enhance selectivity in cancer therapy, underscoring the importance of understanding the physical aspects of particle uptake. In this study, it was hypothesized that elongated particles might be preferentially taken up by deformable, aggressive cancer cells compared to normal cells. Two film-stretching methods were tested for 0.
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