Purpose: The main objective of this study was to evaluate the efficacy of tungsten carbide as new lead-free radiation shielding material in nuclear medicine by evaluating the attenuation properties.
Materials And Methods: The elemental composition of tungsten carbide was analysed using Field-Emission Scanning Electron Microscopy (FESEM) with energy dispersive X-ray (EDX). The purity of tungsten carbide was 99.9%, APS: 40-50 µm. Three discs of tungsten carbide was fabricated with thickness of 0.1 cm, 0.5 cm and 1.0 cm. Three lead discs with similar thickness were used to compare the attenuation properties with tungsten carbide discs. Energy calibration of gamma spectroscopy was performed by using I, Ba, Eu, and Cs. Gamma radiation from these sources were irradiated on both materials at energies ranging from 0.160 MeV to 0.779 MeV. The experimental attenuation coefficients of lead and tungsten carbide were compared with theoretical attenuation coefficients of both materials from NIST database. The half value layer and mean free path of both materials were also evaluated in this study.
Results: This study found that the peaks obtained from gamma spectroscopy have linear relationship with all energies used in this study. The relative differences between the measured and theoretical mass attenuation coefficients are within 0.19-5.11% for both materials. Tungsten carbide has low half value layer and mean free path compared to lead for all thickness at different energies.
Conclusion: This study shows that tungsten carbide has high potential to replace lead as new lead-free radiation shielding material in nuclear medicine.
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http://dx.doi.org/10.1016/j.ejmp.2020.08.017 | DOI Listing |
Minerva Dent Oral Sci
January 2025
Multidisciplinary Department of Medical-Surgical and Dental Specialties, University of Campania Luigi Vanvitelli, Naples, Italy.
Background: The objective of the in vitro study was to evaluate the impact of two adhesive removal techniques on the surface roughness of the human enamel surface using laser scanning confocal microscopy (LSCM).
Methods: Forty healthy first upper molar teeth were included in this experiment (20 teeth per each group). T0 measurement of surface roughness parameter of the teeth were conducted using LSCM.
Langmuir
January 2025
College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China.
Lithium-sulfur (Li-S) batteries hold significant promise due to high energy density, cost-effectiveness, and ecological sustainability, but their practical applications are constrained by suboptimal electrochemical performance and the detrimental shuttle effect. Herein, a porous, sandwich-structured composite was developed to function as a freestanding cathode designed for Li-S batteries without aluminum foil. Porous carbon nanofibers (PCNF) were employed as the conductive matrix for sulfur, with tungsten carbide (WC) being incorporated to furnish abundant active sites for polysulfide adsorption.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
School of Environment and Safety Engineering, North University of China, Taiyuan, Shanxi 030051, PR China.
Energetic composite systems with uniform particle distributions are of considerable interest, but sedimentation is a persisting challenge. Tungsten carbide (WC, density: 15.36 g/cm) particles are promising cemented carbide particles owing to their desirable properties.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Center of Excellence "VERITAS", D. Serikbayev East Kazakhstan Technical University, Ust-Kamenogorsk 070004, Kazakhstan.
This paper reviews recent advances in the synthesis of cobalt-free high-strength tungsten carbide (WC) composites as sustainable alternatives to conventional WC-Co composites. Due to the high cost of cobalt, limited supply, and environmental concerns, researchers are exploring nickel, iron, ceramic binders, and nanocomposites to obtain similar or superior mechanical properties. Various synthesis methods such as powder metallurgy, encapsulation, 3D printing, and spark plasma sintering (SPS) are discussed, with SPS standing out for its effectiveness in densifying and preventing WC grain growth.
View Article and Find Full Text PDFMolecules
December 2024
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China.
Catalyzing hydrogen evolution reaction (HER) is a key process in high-efficiency proton exchange membrane water electrolysis (PEMWE) devices. To replace the use of Pt-based HER catalyst, tungsten carbide (WC) is one of the most promising non-noble-metal-based catalysts with low cost, replicable catalytic performance, and durability. However, the preparation access to scalable production of WC catalysts is inevitable.
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