The first ring-opening addition of a benzylic C(sp)-H bond to azabenzonorbornadienes is demonstrated. The reaction proceeded under the catalytic system of [Cp*CoI(CO)], AgSbF and Fe(OAc) in PhOMe. The methodology showed a good substrate scope with up to 96% yield. The relative configuration of the product was determined as cis-configuration by X-ray crystallography.
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| http://dx.doi.org/10.1039/d0cc05374k | DOI Listing |
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