This Letter proposes and demonstrates a novel, miniature fiber-tip temperature sensor with a tapered hollow capillary tube (HCT) filled with glycerin and dye-doped cholesteric liquid crystal (CLC). The function of glycerin is to provide a surface anchoring force to control the uniform orientation of CLC molecules, so that the CLC in the tapered HCT can be considered as a mirrorless photonic bandgap (PBG) microcavity. An unambiguously identifiable PBG mode single peak appears in the emission spectra of the sensor. The CLC-based fiber-tip temperature sensor has a temperature sensitivity of -9.167/, and the figure of merit can reach 67.4. This sensor offers key features and advantages, including compactness, unambiguous identifiability, and biocompatibility, which can satisfy requirements of temperature measurement in various temperature sensing application fields and has great potential for biochemical detection at cell level. In addition, the CLC was integrated into the optical fiber terminal, and the PBG mode is excited, collected and transmitted by the multimode fiber coupler, which is reported for the first time, to the best of our knowledge.
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http://dx.doi.org/10.1364/OL.402473 | DOI Listing |
Chemphyschem
January 2025
Paderborn University, Department of Chemistry, Warburger Str. 100, D-33098, Paderborn, GERMANY.
Zinc tin oxide (ZTO) is investigated as a photoluminescent sensor for oxygen (O2); chemisorbed oxygen quenches the luminescence intensity. At the same time, ZTO is also studied as a resistive sensor; being an n-type semiconductor, its electrical conductance decreases by adsorption of oxygen. Both phenomena can be exploited for quantitative O2 sensing.
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January 2025
Institute of Biomedical Engineering, College of Medicine, Southwest Jiaotong University, Chengdu 610031, China.
Flexible hydrogel sensors have found extensive applications. However, the insufficient sensing sensitivity and the propensity to freeze at low temperatures restrict their use, particularly in frigid conditions. Herein, a multifunctional eutectogel with high transparency, anti-freezing, anti-swelling, adhesive, and self-healing properties is prepared by a one-step photopolymerization of acrylic acid and lauryl methacrylate in a binary solvent comprising water and deep eutectic solvent (DES).
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January 2025
Mizan-Tepi University, Tepi, Ethiopia.
Integrating noble metal nanostructures, specifically silver nanoparticles, into sensor designs has proven to enhance sensor performance across key metrics, including response time, stability, and sensitivity. However, a critical gap remains in understanding the unique contributions of various synthesis parameters on these enhancements. This study addresses this gap by examining how factors such as temperature, growth time, and choice of capping agents influence nanostructure shape and size, optimizing sensor performance for diverse conditions.
View Article and Find Full Text PDFDalton Trans
January 2025
State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, No. 2 Linggong Road, Dalian 116024, P. R. China.
Molecular materials that exhibit synergistic coupling between luminescence and spin-crossover (SCO) behaviors hold significant promise for applications in molecular sensors and memory devices. However, the rational design and underlying coupling mechanisms remain substantial challenges in this field. In this study, we utilized a luminescent complementary ligand pair as an intramolecular luminophore to construct a new Fe-based SCO complex, namely [FeLL](BF)·HO (1-Fe, L is a 2,2':6',2''-terpyridine (TPY) derivative ligand and L is 2,6-di-1-pyrazol-1-yl-4-pyridinecarboxylic acid), and two isomorphic analogs (2-Co, [CoLL](BF)·HO and 3-Zn, [ZnLL](BF)·HO).
View Article and Find Full Text PDFACS Sens
January 2025
State Key Laboratory of Materials Processing and Die Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology (HUST), No. 1037, Luoyu Road, Wuhan 430074, P. R. China.
High selectivity and sensitivity sensing of HS gas play a decisive role in the early detection of sulfide solid-state battery failure. Herein, we construct the CsPbBr perovskite-based sensor that exhibits outstanding gas-sensing performance to HS at room temperature, including high selectivity, fast response/recovery speed (73.5/275.
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