Monitoring of Anthracene Using Nanoscale Au-Cu Bimetallic Alloy Nanoparticles Synthesized with Various Compositions.

Bimetallic alloy Au-Cu nanoparticles (Au-Cu alloy NPs) were synthesized using a chemical reduction method for sensing applications. Electronic absorption spectroscopy (UV-visible spectroscopy), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used for the confirmation and morphological studies of the synthesized nanoparticles. The composition of Au-Cu alloy NPs was studied by energy-dispersive spectroscopy (EDS). The high crystallinity of Au-Cu alloy NPs was demonstrated by XRD analysis. Both XRD and SEM analyses revealed that the nanoparticles' size ranges from 15 to 25 nm. Pyrrole was polymerized into polypyrrole (PPy) over a neat and clean glassy carbon electrode (GCE) by potentiodynamic polymerization. The sensitivity of GCE was improved by modifying it into a composite electrode. The composite electrode was developed by coating GCE with an overoxidized PPy polymer followed by Au-Cu alloy NPs. The ratio of Au and Cu was carefully controlled. The composite electrode (PPyox/Au-Cu/GCE) successfully detected an environmental toxin anthracene with a detection limit of 0.15 μM, as evidenced by cyclic voltammetry (CV), square-wave voltammetry (SWV), and electrochemical impedance spectroscopy (EIS).