This paper reports the results of the influence of the energy of laser pulses during laser ablation on the morphology and electro-physical properties of LiNbO nanocrystalline films. It is found that increasing laser pulse energy from 180 to 220 mJ results in the concentration of charge carriers in LiNbO films decreasing from 8.6 × 10 to 1.0 × 10 cm, with the mobility of charge carriers increasing from 0.43 to 17.4 cm/(V·s). In addition, experimental studies of sublayer material effects on the geometric parameters of carbon nanotubes (CNTs) are performed. It is found that the material of the lower electrode has a significant effect on the formation of CNTs. CNTs obtained at the same growth time on a sample with a Cr sublayer have a smaller diameter and a longer length compared to samples with a V sublayer. Based on the obtained results, the architecture of the energy nanogenerator is proposed. The current generated by the nanogenerator is 18 nA under mechanical stress of 600 nN. The obtained piezoelectric nanogenerator parameters are used to estimate the parameters of the hybrid-carbon-nanostructures-based piezoelectric energy converter. Obtained results are promising for the development of efficient energy converters for alternative energy devices based on lead-free ferroelectric films.
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http://dx.doi.org/10.3390/ma13183984 | DOI Listing |
Adv Mater
January 2025
Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering, Chongqing University, Chongqing, 400044, China.
Structural diversity of biomolecules leads to various supramolecular organizations and asymmetric architectures of self-assemblies with significant piezoelectric response. However, the piezoelectricity of biomolecular self-assemblies has not been fully explored and the relationship between supramolecular structures and piezoelectricity remains poorly understood, which hinders the development of piezoelectric biomaterials. Herein, for the first time, the piezoelectricity of vitamin-based self-assemblies for power generation is systematically explored.
View Article and Find Full Text PDFAdv Mater
January 2025
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China.
New types of metal-organic framework (MOF) materials have great potential in solving the current global dilemma on energy, environment, and medical care. Herein, based on two kinds of biomolecule-MOFs (Bio-MOFs) with favorable biocompatibility and degradation-reconstruction characteristics, we have established a self-powered muti-functional device to achieve an efficient and broad-spectrum environmental energy collection and biomedical applications. Combining Zn(II) and carnosine-based Zn-Car_MOF possessing a high piezoelectric response (d = 11.
View Article and Find Full Text PDFSci Adv
January 2025
NEST, Istituto Nanoscienze-CNR and Scuola Normale Superiore, I-56127 Pisa, Italy.
While piezoelectric sensing and energy-harvesting devices still largely rely on inorganic components, biocompatible and biodegradable piezoelectric materials, such as cellulose nanocrystals, might constitute optimal and sustainable building blocks for a variety of applications in electronics and transient implants. To this aim, however, effective methods are needed to position cellulose nanocrystals in large and high-performance architectures. Here, we report on scalable assemblies of cellulose nanocrystals in multilayered piezoelectric systems with exceptional response, for various application scopes.
View Article and Find Full Text PDFResearch (Wash D C)
January 2025
School of Physics & Wuhan National Laboratory for Optoelectronics (WNLO), Huazhong University of Science and Technology (HUST), Wuhan 430074, China.
After years of research and development, flexible sensors are gradually evolving from the traditional "electronic" paradigm to the "ionic" dimension. Smart flexible sensors derived from the concept of ion transport are gradually emerging in the flexible electronics. In particular, ionic hydrogels have increasingly become the focus of research on flexible sensors as a result of their tunable conductivity, flexibility, biocompatibility, and self-healable capabilities.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
School of Chemical Sciences, National Institute of Science Education and Research Bhubaneswar, Jatni, Khurda, Odisha, 752050, India.
CuI cubane-type secondary building units are reticulated with a piperazine linker at room temperature to crystallize the metal-organic frameworks (MOFs) CuI(Pip) in a non-centrosymmetric 622 space group. For the first time, cubane cluster type MOF's strong piezoelectric nature has been studied by switching spectroscopy piezo force microscopy (SS-PFM) and piezo force microscopy (PFM) mapping of the crystal, with piezoelectric constant () ∼52.33 pm V, highlighting its potential for mechanical energy harvesting processes.
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