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Spatial Separation of the Conformers of Methyl Vinyl Ketone. | LitMetric

Spatial Separation of the Conformers of Methyl Vinyl Ketone.

J Phys Chem A

Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg, Germany.

Published: October 2020

AI Article Synopsis

Article Abstract

Methyl vinyl ketone (CHO) is a volatile, labile organic compound of importance in atmospheric chemistry. We prepared a molecular beam of methyl vinyl ketone with a rotational temperature of 1.2(2) K and demonstrated the spatial separation of the and conformers of methyl vinyl ketone using the electrostatic deflector. The resulting sample density was 1.5(2) × 10 cm for the direct beam in the laser ionization region. These conformer-selected methyl vinyl ketone samples are well suited for conformer-specific chemical reactivity studies such as in Diels-Alder cycloaddition reactions.

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Source
http://dx.doi.org/10.1021/acs.jpca.0c05893DOI Listing

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