SrTiO_{3} is an incipient ferroelectric that is believed to exhibit a prototype displacive, soft mode ferroelectric transition when subjected to mechanical stress or alloying. We use high-angle annular dark-field imaging in scanning transmission electron microscopy to reveal local polar regions in the room-temperature, paraelectric phase of strained SrTiO_{3} films, which undergo a ferroelectric transition at low temperatures. These films contain nanometer-sized domains in which the Ti columns are displaced. In contrast, these nanodomains are absent in unstrained films, which do not become ferroelectric. The results show that the ferroelectric transition of strained SrTiO_{3} is an order-disorder transition. We discuss the impact of the results on the nature of the ferroelectric transition of SrTiO_{3}.
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http://dx.doi.org/10.1103/PhysRevLett.125.087601 | DOI Listing |
Materials (Basel)
January 2025
Institute of Technology, University of the National Education Commission, Podchorążych 2, 30-084 Kraków, Poland.
In this work, three composite materials based on Terfenol-D and PZT-type material were obtained with a classic sintering method using a combination of 0-3 phases, where the ferroelectric phase was doped PZT material (P) and the magnetic phase was Terfenol-D (T). The percentage of P and T components in the composites was variable, i.e.
View Article and Find Full Text PDFSoft Matter
January 2025
Department of Materials Science, University of Patras, 26504 Patras, Greece.
Monte Carlo molecular simulations of curve-shaped rods show the propensity of such shapes to polymorphism revealing both smectic and polar nematic phases. The nematic exhibits a nanoscale modulated local structure characterized by a unique, polar, -symmetry axis that tightly spirals generating a mirror-symmetry-breaking organization of the achiral rods-form chirality. A comprehensive characterization of the polarity and its symmetries in the nematic phase confirms that the nanoscale modulation is distinct from the elastic deformations of a uniaxial nematic director in the twist-bend nematic phase.
View Article and Find Full Text PDFAdv Mater
January 2025
Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics, Southeast University, Nanjing, 211189, P. R. China.
Utilizing the correlation among diverse physical properties to facilitate multiplexing and multistate memory is anticipated to emerge as an efficient strategy to enhance memory capacity, achieve device miniaturization, and ensure information security. As an important functional material, ferroelectrics have long been considered as a potential candidate in multistate memory devices. Furthermore, the integration of optical response offers an alternative path to realizing multiplexing features, further enhancing the versatility and efficiency of these devices.
View Article and Find Full Text PDFNat Commun
January 2025
School of Physics and Astronomy, University of Nottingham, Nottingham, UK.
Ferroelectrics based on van der Waals semiconductors represent an emergent class of materials for disruptive technologies ranging from neuromorphic computing to low-power electronics. However, many theoretical predictions of their electronic properties have yet to be confirmed experimentally and exploited. Here, we use nanoscale angle-resolved photoemission electron spectroscopy and optical transmission in high magnetic fields to reveal the electronic band structure of the van der Waals ferroelectric indium selenide (α-InSe).
View Article and Find Full Text PDFAdv Mater
January 2025
Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.
Achieving optimal capacitive energy storage performance necessitates the integration of high energy storage density, typical of ferroelectric dielectrics, with the low polarization loss associated with linear dielectrics. However, combining these characteristics in a single dielectric material is challenging due to the inherent contradictions between the spontaneous polarization of ferroelectric dielectrics and the adaptability of linear dielectrics to changes in the electric field. To address this issue, a linear isotactic sulfonylated polynorbornene dielectric characterized by ferroelectric-like crystals has been developed.
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