Order-Disorder Ferroelectric Transition of Strained SrTiO_{3}.

Phys Rev Lett

Materials Department, University of California, Santa Barbara, California 93106-5050, USA.

Published: August 2020

SrTiO_{3} is an incipient ferroelectric that is believed to exhibit a prototype displacive, soft mode ferroelectric transition when subjected to mechanical stress or alloying. We use high-angle annular dark-field imaging in scanning transmission electron microscopy to reveal local polar regions in the room-temperature, paraelectric phase of strained SrTiO_{3} films, which undergo a ferroelectric transition at low temperatures. These films contain nanometer-sized domains in which the Ti columns are displaced. In contrast, these nanodomains are absent in unstrained films, which do not become ferroelectric. The results show that the ferroelectric transition of strained SrTiO_{3} is an order-disorder transition. We discuss the impact of the results on the nature of the ferroelectric transition of SrTiO_{3}.

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http://dx.doi.org/10.1103/PhysRevLett.125.087601DOI Listing

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