In this review, various systems developed in recent years which aim to control dynamic helicity at the macro- and supramolecular level are discussed. The strong interactions between the individual molecular components in these controlled helical assemblies, ranging from columnar aggregates to helical polymers and cholesteric liquid crystals, result in stereoinduction from the molecular level to the level of these macro- and supramolecular helical architectures. Therefore these systems are potentially useful for various applications, including responsive materials and chirality sensors and amplifiers.
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http://dx.doi.org/10.1039/b801886c | DOI Listing |
ACS Macro Lett
January 2025
Key Laboratory of Materials Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Materials Chemistry and Service Failure, Hubei Engineering Research Center for Biomaterials and Medical Protective Materials, State Key Laboratory of Materials Processing and Die & Mould Technology, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
As a special kind of supramolecular compound with many favorable properties, pillar[]arene-based supramolecular polymer networks (SPNs) show potential application in many fields. Although we have come a long way using pillar[]arene to prepare SPNs and construct a series of smart materials, it remains a challenge to enhance the mechanical strength of pillar[]arene-based SPNs. To address this issue, a new supramolecular regulation strategy was developed, which could precisely control the preparation of pillar[]arene-based SPN materials with excellent mechanical properties by adjusting the polymer network structures.
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January 2025
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China.
Two-dimensional layered structural materials exhibit a wide range of properties due to their ultrahigh specific surface area. However, achieving ordered exfoliation to obtain uniform two-dimensional structures remains challenging. In this study, we developed a supramolecular system by covalently bonding hexathiobenzene (HB) into β-cyclodextrin to create a light-responsive moiety, followed by coassembly with bipyridine and nickel ions to form a polypseudorotaxane (PR) system, which enables an light-induced exfoliation strategy for two-dimensional materials.
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January 2025
School of Chemistry and Molecular Engineering, Nanjing Tech University, 211816 Nanjing, China.
The construction of single-component, white-light-emitting, conjugated polymers always utilizes fluorescence resonance energy transfer (FRET) for efficient emission. However, the main challenges in developing such materials primarily come from the effects of aggregation states during solution processing and the precise structural control required for the synthesis of compounds. Both aspects can affect the FRET between different lumophores in white-light-emitting materials.
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January 2025
School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China.
Injectable behavior is often observed in polymer-based hydrogels yet is rarely achieved in low-molecular-weight hydrogels (LMWHs), the realization of which may boost the development of new soft materials for biomedical applications. Here, we report on injectable self-healing and antidissolving LMWHs that are formed through a simple ionic cross-linking strategy, showing a fundamental application for the encapsulation of living cells. The LMWHs are formed by simply mixing Ca with negatively charged supramolecular polymers.
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January 2025
Department of Chemical & Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States.
Host-guest interactions have been increasingly explored for use in the dynamic physical cross-linking of polymeric precursors to form hydrogel networks. However, the orientation of guest motifs is restricted upon macromolecule conjugation. The implications of such restriction on both the kinetics and thermodynamics of the resulting host-guest supramolecular cross-links are poorly understood.
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