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Modification of Graphitic Carbon Nitride with Hydrogen Peroxide. | LitMetric

Modification of Graphitic Carbon Nitride with Hydrogen Peroxide.

Nanomaterials (Basel)

Department of Chemistry, VŠB-Technical University of Ostrava, 70800 Ostrava, Czech Republic.

Published: September 2020

AI Article Synopsis

  • Graphitic carbon nitride (GCN) was created by heating melamine and then was thermally exfoliated in air for 1-3 hours.
  • *Both bulk and exfoliated GCN were treated with 10-30% aqueous hydrogen peroxide solutions to study their modification.
  • *Changes in photocatalytic activities and surface properties were observed, although the overall GCN structure remained unchanged according to the tests conducted with Acid Orange 7 and Rhodamine B.

Article Abstract

Graphitic carbon nitride (GCN) was synthetized by heating melamine and then it was thermally exfoliated for 1-3 h in air. Both bulk and exfoliated GCN nanomaterials were treated in the 10-30% aqueous solutions of HO for us to study their modification. The light absorption properties were observed by the reddish color and the red-shifts of their UV-Vis spectra. The content of oxygen increased and hydrogen peroxide was supposed to partially oxidize C-OH groups to C=O ones and to form C-O-C groups instead of edge C-NH-C ones. The GCN structure changes were not observed. However, a surface modification of the GCN materials was recognized by their changed photocatalytic activities tested by means of Acid Orange 7 (AO7) and Rhodamines B (RhB), zeta-potentials, and neutralization titration curves.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7559342PMC
http://dx.doi.org/10.3390/nano10091747DOI Listing

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