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Hydroxyl Spillover in Fe-Se Dual-Site Catalysts for Mixed Plastics Assay.
J Am Chem Soc
December 2024
State Key Laboratory of Green Pesticide, International Joint Research Center for Intelligent Biosensing Technology and Health, College of Chemistry, Central China Normal University, Wuhan 430079, P. R. China.
The complex composition of real plastic wastes poses a significant challenge for their large-scale disposal. A responsive on-site compositional analysis of plastics is informative in choosing downstream processing methods. Nanocatalyst-based assay kit is highly qualified for this scene; however, there remain no efficient nanocatalysts for plastics due to their highly inert chemistry.
View Article and Find Full Text PDFO Cleavage at a Preorganized Triiron Cluster.
J Am Chem Soc
December 2024
Department of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.
In Nature, the four-electron reduction of O is catalyzed at preorganized multimetallic active sites. These complex active sites often feature low-coordinate, redox-active metal centers precisely positioned to facilitate rapid O activation processes that obviate the generation of toxic, partially reduced oxygen species. Very few biomimetic constructs simultaneously recapitulate the complexity and reactivity of these biological cofactors.
View Article and Find Full Text PDFPrediction of total lipids and fatty acids in black soldier fly (Hermetia illucens L.) dried larvae by NIR-hyperspectral imaging and chemometrics.
Spectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Food Engineering, School of Food Engineering, University of Campinas, Campinas, SP, Brazil. Electronic address:
The unique fatty acid composition of BSF larvae oil makes it suitable for various applications, including use in animal feed, aquaculture, biodiesel production, biomaterials, and the food industry. Determination of BSF larvae composition usually requires analytical methods with chemicals, thus needing emerging techniques for fast characterization of its composition. In this study, Near Infrared Hyperspectral Imaging (NIR-HSI) (928 - 2524 nm) coupled with chemometrics was applied to predict the lipid content and fatty acid composition in intact black soldier fly (BSF) larvae.
View Article and Find Full Text PDFEffect of acute treatment with the glucagon-like peptide-1 receptor agonist, liraglutide, and estrus phase on cue- and drug-induced fentanyl seeking in female rats.
Behav Pharmacol
December 2024
Department of Neural and Behavioral Sciences.
Opioid use disorder (OUD) is a crisis in the USA. Despite advances with medications for OUD, overdose deaths have continued to rise and are largely driven by fentanyl. We have previously found that male rats readily self-administer fentanyl, with evident individual differences in fentanyl taking, seeking, and reinstatement behaviors.
View Article and Find Full Text PDFVicarious Trauma via the Observation of Extremist Atrocities: A Rapid Evidence Assessment.
Trauma Violence Abuse
December 2024
College of Public Health, Department of Social Work, George Mason University, VA, USA.
Researchers are increasingly conducting research using primary source data involving observation of, and exposure to, violent extremist individuals, their acts, their online content, and the ideologies that they act in support of. Of concern is that this increased use of primary source material has not occurred alongside a serious investigation of the traumatic outcomes that may result from constant exposure to such materials within the process of conducting academic research. As such, the goal of this review is to conduct a rapid evidence assessment to identify (a) What theories currently exist that conceptualize trauma stemming from vicarious observation of extremist atrocities? (b) In what similar domains (if any) have researchers conceptualized the trauma that stems from vicarious observation of extremist atrocities? (c) What is the current evidence base for these theories? And (d) What are the immediate research needs to extend this research and support the research workforce? Articles were identified using search strings related to types of trauma, and relevant domains of work (e.
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