US Food and Drug Administration (FDA) allowed for direct addition of castor oil for human consumption as food and most recently FDA approved castor oil as over-the-counter (OTC) for laxative drug. The present article highlights the green route phosphorylation of castor oil (COL) via condensation polymerization. Further, the incorporation of metal ions Cu (II)) and Zn (II) into the polymer matrix have been carried out at elevated temperature using catalyst p-toluene sulphonic acid (PTSA). The modification of the said material has been confirmed by FT-IR, UV-VIS, and H and P-NMR spectroscopy. Further, the i antibacterial activities of the metal incorporated-COL has been performed by standard methods against (MCC2243) (gram-positive) and (MCC2412) (gram-negative) bacteria. The results revealed that the incorporation of metal ions into the polymer matrix increases the antibacterial activity largely. This may be governed by the electrostatic interaction between metal ions and microbes, also the generation of free active oxygen hinders the normal activity of bacteria. These results suggest that the synthesized material may act a potential candidate for low cost, environment friendly antibacterial agents and may find their application in clinical fields. Herein we are also proposing mechanism of antibacterial activity.
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http://dx.doi.org/10.1016/j.molstruc.2020.129091 | DOI Listing |
Heliyon
January 2025
Department of Mechanical Engineering, Addis Ababa Science and Technology University, Addis Ababa, 16417, Ethiopia.
Many approaches have been implemented in order to reduce the emissions of particular pollutants without compromising engine performance. Cotton and castor mixed seed oil was chosen for the current study due to their distinct fatty acid composition and potential as a feedstock for bio-additives. Three fuel samples-99 % diesel and 1 % blended fuel (cottonseed oil + castor seed oil), 99.
View Article and Find Full Text PDFMolecules
January 2025
Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, HR 10000 Zagreb, Croatia.
Rhabdophane, CePO∙HO, nanoparticles were prepared by mechanochemical synthesis with different durations and thoroughly characterized by various characterization techniques. X-ray diffraction analysis showed that the optimal synthesis duration was 15 min, since, in this case, pure rhabdophane is obtained, without traces of contamination by the vessel material. The size of the obtained nanoparticles, as determined from high-resolution transmission electron microscopy images, was around 5 nm.
View Article and Find Full Text PDFRSC Adv
January 2025
High-Tech Research and Development Center, Kim Il Sung University Pyongyang Democratic People's Republic of Korea
In this study, we synthesized a water-based, rosin-modified, polymerized oil (WRPO) an addition and polymerization reaction of dehydrated castor oil (DCO), rosin acid (RA), zinc resinate (ZR) and dehydrated castor oil acid (DCOA). Addition and polymerization reactions at 240 °C, followed by neutralization with ammonia, dissolution into butyl alcohol and subsequent dilution with water, were performed at varying DCOA contents of 10%, 20%, 30%, 35% and 40%. WRPO was mixed with butoxymethylmelamine (BMM), a curing agent, at a weight ratio of 80 : 20, and then cured for 2 hours at 130 °C.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
A series of biomass-based linear aliphatic polyesters are synthesized by combining sebacic acid (SA) (C10 diacid) and 1,18-octadecanedioic acid (OA) (C18 diacid) with a series of diols with varied alkyl chain lengths (C2 to C10 diols). SA and OA are obtainable from castor oil and palm oil, respectively. The reaction extent (polymerization extent) is high (≥96%) in all cases, and the number-average molecular weight (M) is 10 000-43 000 g mol after purification.
View Article and Find Full Text PDFChemSusChem
January 2025
TU Dortmund University, Department for Biochemical and Chemical Engineering, Laboratory of Industrial Chemistry, Emil-Figge-Straße 66, 44227, Dortmund, Germany.
Platform chemicals from renewable resources with broad applications are highly desirable, particularly for replacing fossil-based monomers. Bifunctional aliphatic ester-aldehydes, accessible via regioselective hydroformylation of unsaturated oleochemicals, can be converted into linear ω-amino/ω-hydroxy esters and dicarboxylic acids-key building blocks for biobased aliphatic polycondensates. However, their success hinges on efficient, economically viable production, with catalyst recycling being critical.
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