Novel bionanocomposite films were prepared by combining konjac glucomannan/surface deacetylated chitin nanofibers (KGM/S-ChNFs) with different concentrations of citric acid (CA) (10%-25%) via a solution casting method. The effect of CA-induced crosslinking on the rheological behavior of film-forming solutions (FFS) as well as the structural and physicochemical properties of the resulting bionanocomposite films were evaluated. The results revealed that the increased CA loadings increased the shear viscosity of FFS. Fourier transform infrared spectra and scanning electron microscopy results confirmed the successful crosslinking between CA and S-ChNFs. The addition of 20 wt% CA was defined as the optimal condition, resulting in minimum water sensitivity and permeability, while maintaining a good combination of tensile strength and antimicrobial properties. This work supported the conclusion that CA crosslinking was an effective pathway for the preparation of polysaccharide-based bionanocomposite films with improved properties, which may be a promising material for active food packaging applications.
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http://dx.doi.org/10.1016/j.ijbiomac.2020.08.138 | DOI Listing |
J Food Sci
January 2025
Nutrition Research Center, Department of Food Science and Technology, Faculty of Nutrition and Food Sciences, Tabriz University of Medical Sciences, Tabriz, Iran.
Alternatives to nonbiodegradable synthetic plastics for food packaging include films made from biopolymers that are nontoxic and environment-friendly. In this study, carnauba wax (CW) and nitrogen-doped graphene quantum dots (NG) as functional additives were utilized in the production of pectin/gelatin (PG) film. NG was synthesized through the microwave method, using acetic acid as the carbon source, giving size, and zeta potential of 1.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical Engineering, Khalifa University, P.O. Box 127788, Abu Dhabi, United Arab Emirates; Food Security and Technology Center, Khalifa University of Science and Technology, P. O. Box 127788, Abu Dhabi, United Arab Emirates. Electronic address:
Packaging made of plastic harms the environment. Thus, polysaccharide edible films are becoming a popular food packaging solution. Alginate is a biopolymer derived from seaweed that has the potential to create food packaging materials that are environmentally friendly and biodegradable.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Biotransformation and Organic Biocatalysis Research Group, Department of Exact Sciences, Santa Cruz State University, 45654-370 Ilhéus, Brazil. Electronic address:
This study explored the synergistic combination of silver nanoparticles (AgNPs), eucalyptus-derived nanofibrillated cellulose (NFC) and cassava starch to develop bionanocomposites with advanced properties suitable for sustainable and antifungal packaging applications. The influence of AgNPs synthesized through a green method using cocoa bean shell combined with varying concentrations of NFC were investigated. Morphological (scanning electron microscopy and atomic force microscopy), optical (L*, C*, °hue, and opacity), chemical (Fourier transform infrared spectroscopy), mechanical (puncture force, tensile strength, and Young's modulus), rheological (flow curve and frequency sweeps, strain, and stress), barrier, and hydrophilicity properties (water vapor permeability, solubility, wettability, and contact angle), as well as the antifungal effect against pathogens (Botrytis cinerea, Penicillium expansum, Colletotrichum musae, and Fusarium semitectum), were analyzed.
View Article and Find Full Text PDFCompr Rev Food Sci Food Saf
January 2025
School of Food Science and Engineering, Hainan University, Haikou, China.
In recent years, biopolymer-based food packaging films have emerged as promising alternatives to petroleum-based plastic food packaging films. Various additives have been explored to enhance their properties, and one such group of additives is natural plant aldehydes. These aldehydes are commonly employed to improve the antibacterial and antioxidant properties of biopolymer-based food packaging films.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
University of Jeddah, College of Science, Department of Physical Sciences, Jeddah, Saudi Arabia. Electronic address:
This study explores the synthesis and characterization of bio-nanocomposite films composed of HPMC/PVA/CMC blends with molybdenum trioxide (MoO₃) nanofillers at varying concentrations. X-ray diffraction (XRD) analysis confirms the structural integrity of the polymer matrix, with MoO₃ enhancing crystallinity as its concentration increases. Fourier-transform infrared spectroscopy (FTIR) reveals strong hydrogen bonding between MoO₃ and the polymer matrix, leading to improved interfacial compatibility.
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