5-Carbonyl-1,3-oxazine-2,4-diones from -Cyanosulfoximines and Meldrum's Acid Derivatives.

At elevated temperatures, -cyanosulfoximines react with Meldrum's acid derivatives to give sulfoximines with -bound 5-carbonyl-1,3-oxazine-2,4-dione groups. A representative product was characterized by single-crystal X-ray structure analysis. The product formation involves an unexpected molecular reorientation requiring several sequential bond-forming and -cleaving processes.