The class of organic-inorganic lead halides with perovskite crystal structures has recently emerged as promising materials for a variety of practical optoelectronic applications. In particular, hybrid halide perovskite quantum dots possess excellent intrinsic optoelectronic properties such as high color purity (full width at half-maximum of 24.59 nm) and photoluminescence quantum yields (92.7%). In this work, we demonstrate the use of perovskite quantum dot materials as an emissive layer of hybrid light-emitting transistors. To investigate the working mechanism of perovskite quantum dots in light-emitting transistors, we investigated the electrical and optical characteristics under both p-channel and n-channel operation. Using these materials, we have achieved perovskite quantum dot light-emitting transistors with high electron mobilities of up to 12.06 cm·V s, high brightness of up to 1.41 × 10 cd m, and enhanced external quantum efficiencies of up to 1.79% operating at a source-drain potential of 40 V.
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http://dx.doi.org/10.1021/acsami.0c05537 | DOI Listing |
Sci Adv
January 2025
State Key Laboratory of Extreme Photonics and Instrumentation, College of Optical Science and Engineering, International Research Center for Advanced Photonics, Zhejiang University, Hangzhou 310027, China.
Solution-processed semiconductor lasers are next-generation light sources for large-scale, bio-compatible and integrated photonics. However, overcoming their performance-cost trade-off to rival III-V laser functionalities is a long-standing challenge. Here, we demonstrate room-temperature continuous-wave perovskite polariton lasers exhibiting remarkably low thresholds of ~0.
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January 2025
MIIT Key Laboratory of Advanced Display Materials and Devices, Jiangsu Province Engineering Research Center of Quantum Dot Display, School of Materials Science and Engineering, Institute of Optoelectronics & Nanomaterials, Nanjing University of Science and Technology, Nanjing, Jiangsu 210094, China.
Room temperature (RT) synthesized mixed bromine and chlorine CsPbBrCl perovskite quantum dots (Pe-QDs) offer notable advantages for blue quantum dot light-emitting diodes (QLEDs), such as cost-effective processing and narrow luminescence peaks. However, the efficiency of blue QLEDs using these RT-synthesized QDs has been limited by inferior crystallinity and deep defect presence. In this study, we demonstrate a precise approach to constructing high-quality gradient core-shell (CS) structures of CsPbBrCl QD through anion exchange.
View Article and Find Full Text PDFNano Lett
January 2025
Department of Physics, Hong Kong Institute for Advanced Study, City University of Hong Kong, Kowloon, Hong Kong 999077, China.
Superconductivity in infinite-layer nickelates has stirred much research interest, to which questions regarding the nature of superconductivity remain elusive. A critical leap forward to address these intricate questions is through the growth of high-crystallinity infinite-layer nickelates, including the "parent" phase. Here, we report the synthesis of a high-quality thin-film nickelate, NdNiO.
View Article and Find Full Text PDFSmall
January 2025
Chair for Emerging Electronic Technologies, TUD Dresden University of Technology, Nöthnitzer Straße 61, 01187, Dresden, Germany.
The stability of perovskite quantum dot solar cells is one of the key challenges of this technology. This study reveals the unique degradation behavior of cesium lead triiodide (CsPbI) quantum dot solar cells. For the first time, it is shown that the oxygen-induced degradation and performance loss of CsPbI quantum dot photovoltaic devices can be reversed by exposing the degraded samples to humidity, allowing the performance to recover and even surpass the initial performance.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Department of Chemistry, Yonsei University, Wonju, Gangwon 26493, Korea.
Understanding the environment-dependent stability and photoluminescence (PL) properties of advanced perovskite materials remains a challenge with conflicting views. Herein, we investigated the influence of the host matrix (poly(methyl methacrylate) (PMMA) and polystyrene (PS)) and atmospheric conditions (ambient and N) on the PL properties of a CsPbBr perovskite quantum dot (PQD) using single-particle spectroscopy. Despite the same PL blinking mechanism, the PL properties of the PQD were considerably affected by the environmental conditions.
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