Enantiopure aziridin-2-yl methanols - are used as highly effective sensors for enantiodiscrimination of α-racemic carboxylic acids containing tertiary or quaternary stereogenic centers. A linear correlation between theoretical and observed % ee values for CSA- and enantiomerically enriched samples of mandelic acid has been observed, indicating the possible application of these compounds in the ee determination. The free NH and OH groups in - ensure good recognition.
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Optically Pure Aziridin-2-yl Methanols as Readily Available H NMR Sensors for Enantiodiscrimination of α-Racemic Carboxylic Acids Containing Tertiary or Quaternary Stereogenic Centers.
J Org Chem
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Department of Organic and Applied Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, Poland.
Enantiopure aziridin-2-yl methanols - are used as highly effective sensors for enantiodiscrimination of α-racemic carboxylic acids containing tertiary or quaternary stereogenic centers. A linear correlation between theoretical and observed % ee values for CSA- and enantiomerically enriched samples of mandelic acid has been observed, indicating the possible application of these compounds in the ee determination. The free NH and OH groups in - ensure good recognition.
View Article and Find Full Text PDF[(2R,3R)-3-(4-Nitro-phen-yl)aziridin-2-yl]methanol monohydrate.
Acta Crystallogr Sect E Struct Rep Online
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UMR 990, INSERM, Université d'Auvergne, Laboratoire de Chimie Physique, Faculté de Pharmacie, 63001 Clermont-Ferrand, France.
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