This work aims to obtain activated carbon (AC) from yeast residue to boost up bioeconomy. In this way, carbon was prepared from yeast biomass produced by the ethanol industry and after beta-glucan extraction. Carbon was activated with CO, water vapor, and a combination of both using an experimental design. The best conditions to produce AC were activation with CO for 30 min at 850 °C and CO flow of 0.09 L/min, set by experimental design and desirability function to optimize the yield, surface area, and microporosity. Thus, for physical activation with water vapor employing the optimized conditions, it was possible to achieve a yield of 56.6% (m/m) for AC with 1144 m/g of surface area and mean micropore volume of 0.53 cm/g. The maximum AC surface area reached 1616 ± 567 m/g with a yield of 21 ± 1%. The prepared ACs were characterized by elemental analysis, X-ray diffractometry, infrared spectroscopy, thermogravimetry analysis, pH, and potentiometric titration to determine the main functional groups of sorption sites. The carbon obtained from the desirability condition was used to remove dipyrone from synthetic aqueous effluent with an experimental sorption capacity of 88 ± 4 mg/g, being the phenomenon described by the Freundlich isotherm model.
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Sci Rep
January 2025
Department of Pharmaceutical Chemistry, Semmelweis University, Hőgyes Endre U. 9, 1092, Budapest, Hungary.
Microtiter-plate-based systems are unified platforms of high-throughput experimentation (HTE). These polymeric devices are used worldwide on a daily basis-mainly in the pharmaceutical industry-for parallel syntheses, reaction optimization, various preclinical studies and high-throughput screening methods. Accordingly, laboratory automation today aims to handle these commercially available multiwell plates, making developments focused on their modifications a priority area of modern applied research.
View Article and Find Full Text PDFChin J Traumatol
January 2025
Department of Emergency Surgery and Orthopaedic Surgery, Qilu Hospital of Shandong University, Jinan, 250012, China. Electronic address:
Purpose: The fixation method commonly employed worldwide for treating unstable fractures of the posterior pelvic ring is the percutaneous iliosacral screw technique. However, prolonged operation time and frequent fluoroscopies result in surgical risks. This study aimed to investigate whether a new triangulation method could reduce operative and fluoroscopy times and increase the accuracy of screw placement.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, PR China; Department of Chemistry, Sungkyunkwan University, Suwon, 16419, Republic of Korea. Electronic address:
Background: Estriol (E3) is a common estrogen responsible for regulating the female reproductive system, but excessive amount can pose health risks to humans and wild life. Therefore, sensitive and accurate detection of estriol level is crucial. A novel competitive ECL immunosensor based on a dual signal amplification strategy of AuNPs@GO@SmMoSe and Gd(MoO) was fabricated for ultrasensitive detection of estriol.
View Article and Find Full Text PDFEnviron Res
January 2025
Key Laboratory of Chemical Additives for China National Light Industry, Shaanxi University of Science and Technology, 710021 Xi'an, China.
For the effective removal of phenol from the environment, photocatalytic synergistic adsorption is currently one of the key methods. By leveraging the polysaccharide backbone structure of sodium alginate (SA),Zinc hydroxystannate (ZHS) was introduced into the gel structure using a co-precipitation technique. Additionally, gangue waste was repurposed through a polymerization reaction.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University (GXU), 100 Daxuedong Road, Xixiangtang District, Nanning 530004 China. Electronic address:
Porous carbons with large surface area (>3000 m/g) and heteroatom dopants have shown great promise as electrode materials for zinc ion hybrid capacitors. Centralized mesopores are effective to accelerate kinetics, and edge nitrogen can efficiently enhance pseudocapacitive capability. It is a great challenge to engineer centralized mesopores and edge nitrogen in large-surface-area porous carbons.
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