To examine the dusting performance of a novel solid state Thulium laser device compared to a standard holmium:yttrium-aluminum-garnet (Ho:YAG) device. This study compares a Dornier Medilas H Solvo 35 with an evaluation model of a pulsed solid state thulium:yttrium-aluminum-garnet (Tm:YAG) laser (Dornier MedTech Laser GmbH, Wessling, Germany). The model consisted of a mold with irrigated water at 37°C. For 2-9 minutes, laser fibers were guided by an xy-plotter in spirals over BegoStones. Stone mass was measured before and after laser application. Comparisons to Ho:YAG and further Tm:YAG investigations were performed. Identical settings with similar pulse durations yielded a significant 14% advantage for Ho:YAG in slow fiber speeds and a tendency toward 15% higher efficiency of Tm:YAG in fast fiber speeds. Increased pulse duration in Tm:YAG led significantly to 32%-54% higher ablation rates in comparison to Tm:YAG in both setups. Ablated mass loss range is 102-1107 mg for slow fiber speeds and 22-528 mg for fast speeds. Mass loss is proportional to pulse energy, frequency, and pulse duration, whereas pulse energy defines the penetration depth into the model stones. Frequency characterizes the ablation homogeneity and possible working speeds. Tm:YAG is significantly more efficient when longer pulse durations are used. Identical settings revealed a strong connection to fiber movement speeds. In addition, the Tm:YAG device enables a broader range of settings with the possibility of minimal pulse energy of 100 mJ for low retropulsion and fine dusting with possible frequencies ≤200 Hz.
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http://dx.doi.org/10.1089/end.2020.0525 | DOI Listing |
Dalton Trans
January 2025
Department of Chemistry, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain.
This perpective delves into the emerging field of matere bonds, a novel type of noncovalent interaction involving group 7 elements such as manganese, technetium, and rhenium. Matere bonds, a new member of the σ-hole family where metal atoms act as electron acceptors, have been shown experimentally and theoretically to play significant roles in the self-assembly and stabilization of supramolecular structures both in solid-state and solution-phase environments. This perspective article explores the physical nature of these interactions, emphasizing their directionality and structural influence in various supramolecular architectures.
View Article and Find Full Text PDFActa Crystallogr C Struct Chem
February 2025
Department Chemie, Ludwig-Maximilians Universität, Butenandtstrasse 5-13 (Haus D), D-81377 München, Germany.
The monoprotonated species of 2-aminomalonyl difluoride, namely, 1,3-difluoro-1,3-dioxopropan-2-aminium dihydrogen trifluoride, [CHFNO][HF], was synthesized from sulfur tetrafluoride in anhydrous hydrogen fluoride (aHF) with [NH][CHNO] as the starting material. The solvent was removed and the salt was dissolved in aHF and crystallized. In the solid state, the three-dimensional network is built by medium-strong N-H.
View Article and Find Full Text PDFJ Ion Liq
December 2024
Department of Chemistry and Biochemistry, University of Nevada Las Vegas, 4505 S. Maryland Parkway, Box 454003, Las Vegas, NV 89154, United States.
Dicationic ionic liquids (DILs) are emerging as a powerful, next-generation approach to designing applied ILs because of their superior physicochemical properties as well as their diverse complexity and tunability for task specific applications. DILs are scarce in the literature compared to monocationic ILs (MILs), and one of their main issues is their expected tendency to possess higher melting temperatures. A series of 1,4-bis[2-(4-pyridyl)ethenyl] benzene and 1,4-bis[2-(2-pyridyl)ethenyl]benzene quaternary salts (Q-BPEBs) with different counterions (bromide, tosylate, and triflimide) and carbon chain lengths (C, C, and C) have been synthesized for their potential as DILs with strong photoluminescent properties in the solid state.
View Article and Find Full Text PDFChem Sci
January 2025
School of Materials Science and Engineering, Xiangtan University Xiangtan 411105 China
Poly(ethylene oxide) (PEO)-based solid-state polymer electrolyte (SPE) is a promising candidate for the next generation of safer lithium-metal batteries. However, the serious side reaction between PEO and lithium metal and the uneven deposition of lithium ions lead to the growth of lithium dendrites and the rapid decline of battery cycle life. Building a LiF-rich solid electrolyte interface (SEI) layer is considered to be an effective means to solve the above problems.
View Article and Find Full Text PDFChem Sci
January 2025
Materials Science and Engineering Program, The Graduate School, Florida State University 2005 Levy Ave. Tallahassee FL 32310 USA
Solid electrolytes (SEs) are crucial for advancing next-generation rechargeable battery technologies, but their commercial viability is partially limited by expensive precursors, unscalable synthesis, or low ionic conductivity. Lithium tetrahaloaluminates offer an economical option but exhibit low Li conductivities with high activation energy barriers. This study reports the synthesis of lithium aluminum chalcohalide (LiAlClS) using inexpensive precursors one-step mechanochemical milling.
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