For pseudospin-half bosons with interspin attraction and intraspin repulsion, the normal phase and Bose condensed phase can coexist at finite temperature. The homogeneous system is unstable against the spinodal decomposition within a medium density interval, and, consequently, a normal-superfluid phase separation takes place. The isothermal equation of state shows a characteristic plateau in the P-V (pressure-volume) diagram, which is reminiscent of a classical gas-liquid transition, although, unlike the latter, the coexistence lines never terminate at a critical point as temperature increases. In a harmonic trap, the phase separation can be revealed by the density profile of the atomic cloud, which exhibits a sudden jump across the phase boundary.
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http://dx.doi.org/10.1103/PhysRevLett.125.055301 | DOI Listing |
J Chromatogr A
January 2025
School of Pharmacy, Shenyang Pharmaceutical University, Shenyang 110016, PR China. Electronic address:
Evodiamine, a chiral quinazoline alkaloid in the traditional Chinese medicine Evodiae fructus, exhibited efficacy for CNS diseases. In this study, the pure enantiomers of evodiamine were prepared in large quantities via chemical resolution. Their structures were elucidated by MS, NMR and ECD.
View Article and Find Full Text PDFBioelectrochemistry
January 2025
School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China; Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, People's Republic of China.
Highly stable calcium ion selective electrodes (Ca-ISEs) were developed by drop-casting a layer of poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT: PSS) as an ion-to-electron transfer layer onto Au electrode. The conductive PEDOT: PSS ink was prepared using a metastable liquid-liquid contact (MLLC) doping method, which induced phase separation, removed excess PSS, and significantly enhanced charge transfer kinetics and conductivity. The resulting Ca-ISEs exhibited excellent electrochemical performance.
View Article and Find Full Text PDFACS Nano
January 2025
WA School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia.
Quadruple perovskite oxides have received extensive attention in electronics and catalysis, owing to their cation-ordering structure and intriguing physical properties. However, their repertoires still remain limited. In particular, piezoelectricity from quadruple perovskites has been rarely reported due to the frustrated symmetry-breaking transition in A-site-ordered perovskite structures, disabling their piezoelectric applications.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Department of Instrumentation and Control Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka, India.
Ciprofloxacin (CIP) is an extensively used broad-spectrum, fluoroquinolone antibiotic used for treating diverse bacterial infections. Effluent treatment plants (ETPs) worldwide lack technologies to detect or remediate antibiotics. CIP reaches the aquatic phase primarily due to inappropriate disposal practices, lack of point-of-use sensing, and preloaded activated charcoal filter at ETPs.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Physics, National University of Singapore, Singapore 117551, Singapore.
Phase separation plays a crucial role in many natural and industrial processes, such as the formation of clouds and minerals and the distillation of crude oil. In metals and alloys, phase separation is an important approach often utilized to improve their mechanical strength for use in construction, automobile, and aerospace manufacturing. Despite its importance in many processes, the atomic details of phase separation are largely unknown.
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