Dielectric capacitors with the prominent features of ultrafast charging-discharging rates and ultrahigh power densities are ubiquitous components in modern electronics. To meet the growing demand for electronics miniaturization, dielectric capacitors with high energy storage properties are extensively researched. Here we present an overview of the recent progress in the engineering of multiscale structures of dielectric ceramics ranging from bulk to thin films. This article commences with a brief introduction of the fundamentals of dielectric ceramics, including primary parameters, a library of dielectric ceramics, and multiscale structures. Emphases are placed on the relationship between multiscale structures and energy storage properties and the rational structure design principles in dielectric ceramics. Also included are currently available multilayer ceramic capacitors based on multiscale engineered ceramic structures. Finally, challenges along with opportunities for further research and development of high-performance dielectric ceramics for electrostatic energy storage are highlighted.
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http://dx.doi.org/10.1039/d0nr04479b | DOI Listing |
Sci Rep
December 2024
ENET Centre, VSB- Technical University of Ostrava, Ostrava, Czech Republic.
The present investigation provides an easy and affordable strategy for fabrication of functional ceramics BiNaTiO-SrFeO (BNT-SrF5) thick films on a flexible, inexpensive and electrically integrated substrate using electrophoretic deposition process (EPD). EPD is a widely accepted, environmentally friendly method for applying coatings from a colloidal suspension to conductive substrates. Lead-free ferroelectric BNT-SrF5 powder was synthesized by solid state method to fabricate bulk samples and thick films (30-160 μm) by EPD process.
View Article and Find Full Text PDFHeliyon
December 2024
Department of Glass & Ceramic Engineering, Rajshahi University of Engineering & Technology (RUET), Rajshahi-6204, Bangladesh.
This study explored the structural, optical, antibacterial, and dielectric properties of TiO nanoparticles synthesized using two distinct approaches: sol-gel and biosynthesis. Density functional tight binding (DFTB+) and density functional theory (DFT) calculations were employed alongside experimental techniques to gain a comprehensive understanding of the electronic-property relationships. peel extract was utilized for the biosynthesis method.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Guangxi Universities Key Laboratory of Non-ferrous Metal Oxide Electronic Functional Materials and Devices, College of Material Science and Engineering, Guilin University of Technology, Guilin 541004, China.
A microwave dielectric ceramic based on lithium aluminum silicate (LiAlSiO) with ultralow permittivity was synthesized using the traditional solid-state reaction technique, and its dielectric characteristics at microwave frequencies are presented. The nominal LiAlSiO ceramic exhibited a relative permittivity of 3.95.
View Article and Find Full Text PDFAdv Mater
December 2024
Department of Chemistry and Bioscience, Aalborg University, Aalborg, DK-9220, Denmark.
β-CaSiO based glass-ceramics are among the most reliable materials for electronic packaging. However, developing a CaSiO glass-ceramic substrate with both high strength (>230 MPa) and low dielectric constant (<5) remains challenging due to its polycrystalline nature. The present work has succeeded in synthesizing single-crystalline β-CaSiO for a high-performance glass-ceramic substrate.
View Article and Find Full Text PDFAdv Mater
December 2024
Wuzhen Laboratory, Jiaxing, 314500, P. R. China.
Phase boundary is highly recognized for its capability in engineering various physical properties of ferroelectrics. Here, field-induced polarization rotation is reported in a high-performance (K, Na)NbO-based ferroelectric system at the rhombohedral-tetragonal phase boundary. First, the lattice structure is examined from both macroscopic and local scales, implementing Rietveld refinement and pair distribution function analysis, respectively.
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