Cluster anions [Cp*RuPb] (1) and [Cu@Cp*RuPb] (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C point symmetry and are static on the Pb NMR time scale in solution.
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http://dx.doi.org/10.1039/d0cc03656k | DOI Listing |
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