[Cp*RuPb] and [Cu@Cp*RuPb]: centered and non-centered transition-metal substituted zintl icosahedra.

Chem Commun (Camb)

Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.

Published: September 2020

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Article Abstract

Cluster anions [Cp*RuPb] (1) and [Cu@Cp*RuPb] (2) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo-clusters with C point symmetry and are static on the Pb NMR time scale in solution.

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http://dx.doi.org/10.1039/d0cc03656kDOI Listing

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