Active Materials for Aqueous Zinc Ion Batteries: Synthesis, Crystal Structure, Morphology, and Electrochemistry.

Chem Rev

Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195, United States.

Published: August 2020

AI Article Synopsis

  • Aqueous zinc ion batteries (ZIBs) are emerging as strong options for large-scale energy storage due to their affordability, eco-friendliness, safety, and decent energy density.
  • Despite significant research progress, challenges remain in developing high-performance ZIBs, particularly in finding suitable cathode materials that offer high voltage, fast kinetics, and durability.
  • The text also highlights future research needs, such as improving zinc anodes, finding cost-effective and efficient electrolytes, and choosing compatible current collectors, all aimed at enhancing ZIB efficiency and longevity.

Article Abstract

Aqueous zinc ion batteries (ZIBs) are truly promising contenders for the future large-scale electrical energy storage applications due to their cost-effectiveness, environmental friendliness, intrinsic safety, and competitive gravimetric energy density. In light of this, massive research efforts have been devoted to the design and development of high-performance aqueous ZIBs; however, there are still obstacles to overcome before realizing their full potentials. Here, the current advances, existing limitations, along with the possible solutions in the pursuit of cathode materials with high voltage, fast kinetics, and long cycling stability are comprehensively covered and evaluated, together with an analysis of their structures, electrochemical performance, and zinc ion storage mechanisms. Key issues and research directions related to the design of highly reversible zinc anodes, the exploration of electrolytes satisfying both low cost and good performance, as well as the selection of compatible current collectors are also discussed, to guide the future design of aqueous ZIBs with a combination of high gravimetric energy density, good reversibility, and a long cycle life.

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Source
http://dx.doi.org/10.1021/acs.chemrev.9b00628DOI Listing

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