A highly efficient electrophilic oxyselenation of propargylic amines with diselenides and CO under atmospheric pressure promoted by copper/DTBP is reported. Various biologically important selenyl 2-oxazolidinones were produced in moderate to excellent yields. The developed method features a broad substrate scope, easy scalability, and mild reaction conditions.
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Copper/DTBP-Promoted Oxyselenation of Propargylic Amines with Diselenides and CO: Synthesis of Selenyl 2-Oxazolidinones.
J Org Chem
August 2020
College of Chemistry & Environmental Science, Hebei University, 180 Wusi Donglu, Baoding 071002, P. R. China.
A highly efficient electrophilic oxyselenation of propargylic amines with diselenides and CO under atmospheric pressure promoted by copper/DTBP is reported. Various biologically important selenyl 2-oxazolidinones were produced in moderate to excellent yields. The developed method features a broad substrate scope, easy scalability, and mild reaction conditions.
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