Here, we report the quantitative electroreduction of CO2 to CO by a PNP-pincer iridium(i) complex bearing amino linkers in DMF/water. The electrocatalytic properties greatly depend on the choice of linker within the ligand. The complex 3-N is far superior to the analogues with methylene and oxygen linkers, showing higher activity and better selectivity for CO2 over proton reduction.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d0cc03207g | DOI Listing |
Publication Analysis
Top Keywords
surprisingly big
4
big linker-dependence
4
linker-dependence activity
4
activity selectivity
4
selectivity reduction
4
reduction iridiumi
4
iridiumi pincer
4
pincer complex
4
complex report
4
report quantitative
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!