Kagome-nets, appearing in electronic, photonic and cold-atom systems, host frustrated fermionic and bosonic excitations. However, it is rare to find a system to study their fermion-boson many-body interplay. Here we use state-of-the-art scanning tunneling microscopy/spectroscopy to discover unusual electronic coupling to flat-band phonons in a layered kagome paramagnet, CoSn. We image the kagome structure with unprecedented atomic resolution and observe the striking bosonic mode interacting with dispersive kagome electrons near the Fermi surface. At this mode energy, the fermionic quasi-particle dispersion exhibits a pronounced renormalization, signaling a giant coupling to bosons. Through the self-energy analysis, first-principles calculation, and a lattice vibration model, we present evidence that this mode arises from the geometrically frustrated phonon flat-band, which is the lattice bosonic analog of the kagome electron flat-band. Our findings provide the first example of kagome bosonic mode (flat-band phonon) in electronic excitations and its strong interaction with fermionic degrees of freedom in kagome-net materials.
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http://dx.doi.org/10.1038/s41467-020-17464-2 | DOI Listing |
J Phys Chem Lett
January 2025
Department of Chemistry and Department of Physics, Westlake University, Hangzhou, Zhejiang 310030, China.
Collective strong light-matter coupling provides a versatile means to manipulate physicochemical properties of molecules and materials. Understanding collective polaritonic dynamics is hindered by the macroscopic number of molecules interacting collectively with photonic modes. We develop a many-body theory to investigate the spectroscopy and dynamics of a molecular ensemble embedded in an optical cavity in the collective strong coupling regime.
View Article and Find Full Text PDFPhys Rev Lett
August 2024
Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA.
We present an exact Ansatz for the eigenstate problem of mixed fermion-boson systems that can be implemented on quantum devices. Based on a generalization of the electronic contracted Schrödinger equation (CSE), our approach guides a trial wave function to the ground state of any arbitrary mixed Hamiltonian by directly measuring residuals of the mixed CSE on a quantum device. Unlike density functional and coupled cluster theories applied to electron-phonon or electron-photon systems, the accuracy of our approach is not limited by the unknown exchange-correlation functional or the uncontrolled form of the exponential Ansatz.
View Article and Find Full Text PDFJ Chem Phys
April 2021
Max Planck Institute for Dynamics and Self-Organization, Am Fassberg 11, 37077 Göttingen, Germany.
A five parameter semiempirical Tang-Toennies type model is used to describe the potential curves of the aΣ-state of the heteronuclear polar molecules NaCs, KCs, and RbCs. These molecules are of current interest in experiments at ultra-cold conditions to explore the effects of the strong dipole-dipole forces on the collective many-body quantum behavior. New quantum phenomena are also anticipated in systems consisting of atomic species with different fermion/boson statistics.
View Article and Find Full Text PDFNat Commun
August 2020
Laboratory for Topological Quantum Matter and Spectroscopy (B7), Department of Physics, Princeton University, Princeton, NJ, 08544, USA.
Kagome-nets, appearing in electronic, photonic and cold-atom systems, host frustrated fermionic and bosonic excitations. However, it is rare to find a system to study their fermion-boson many-body interplay. Here we use state-of-the-art scanning tunneling microscopy/spectroscopy to discover unusual electronic coupling to flat-band phonons in a layered kagome paramagnet, CoSn.
View Article and Find Full Text PDFACS Photonics
November 2019
Theory Department, Max Planck Institute for the Structure and Dynamics of Matter - Luruper Chaussee 149, 22761 Hamburg, Germany.
We present a first-principles approach to electronic many-body systems strongly coupled to cavity modes in terms of matter-photon one-body reduced density matrices. The theory is fundamentally nonperturbative and thus captures not only the effects of correlated electronic systems but accounts also for strong interactions between matter and photon degrees of freedom. We do so by introducing a higher-dimensional auxiliary system that maps the coupled fermion-boson system to a dressed fermionic problem.
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