Optical metasurfaces allow the ability to precisely manipulate the wavefront of light, creating many interesting and exotic optical phenomena. However, they generally lack dynamic control over their optical properties and are limited to passive optical elements. In this work, we report the nontrivial infiltration of nanostructured metalenses with three respective nematic liquid crystals of different refractive index and birefringence. The optical properties of the metalens are evaluated after liquid-crystal infiltration to quantify its effect on the intended optical design. We observe a significant modification of the metalens focus after infiltration for each liquid crystal. These optical changes result from modification of local refractive index surrounding the metalens structure after infiltration. We report qualitative agreement of the optical experiments with finite-difference time-domain solver (FDTD) simulation results. By harnessing the tunability inherent in the orientation dependent refractive index of the infiltrated liquid crystal, the metalens system considered here has the potential to enable dynamic reconfigurability in metasurfaces.
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http://dx.doi.org/10.1073/pnas.2006336117 | DOI Listing |
ACS Nano
January 2025
Institute of Photonics and of Nanotechnologies- National Researcher Council (IFN-CNR), LNESS Laboratory, Piazza Leonardo Da Vinci 32, 20133 Milano, Italy.
Manipulating the optical landscape of single quantum dots (QDs) is essential to increase the emitted photon output, enhancing their performance as chemical sensors and single-photon sources. Micro-optical structures are typically used for this task, with the drawback of a large size compared to the embedded single emitters. Nanophotonic architectures hold the promise to modify dramatically the emission properties of QDs, boosting light-matter interactions at the nanoscale, in ultracompact devices.
View Article and Find Full Text PDFLuminescence
January 2025
Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, China.
Currently, the development of red Mn-activated fluoride luminescent materials attracts a lot of attention in optical thermometry sensors, solid lighting, display, and plant growth areas. Nevertheless, the thermal stability of Mn-activated fluoride luminescent materials is still a crucial issue. Herein, a new red RbNaVF:Mn luminescent material with outstanding thermal stability was successfully synthesized through the facial coprecipitation method.
View Article and Find Full Text PDFAdv Mater
January 2025
Liquid Crystals and Photonics Group, Department of Electronics and Information Systems, Ghent University, Technologiepark-Zwijnaarde 126, Ghent, 9052, Belgium.
In liquid crystal (LC) cells, the surface patterning directs the self-assembly of the uniaxial building blocks in the bulk, enabling the design of stimuli-response optical devices with various functionalities. The combination of different anchoring patterns at both substrates can lead to surface induced frustration, preventing a purely planar and defect-free configuration. In cells with crossed assembly of rotating anchoring patterns, elastic deformations allow to obtain a defect-free bulk configuration, but an electrical stimulus can induce disclination lines.
View Article and Find Full Text PDFSmall Methods
January 2025
National Engineering Research Center for Colloidal Materials, Key Laboratory of Colloid and Interface Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China.
Exploring potential third-order nonlinear optical (NLO) materials attracts ever-increasing attention. Given that the atomically precise and rich adjustable structural features of silver nanoclusters (Ag NCs), as well as the unique π-electron conjugated system of carbon-based nanomaterials, a supramolecular co-assembly amplification strategy to enhance the luminescent intensity and NLO performance of the hybrids of the two components, are constructed and the relationship between structures and optical properties are investigated. By combining water soluble Ag NCs [(NH)[Ag(mna)] (Hmna = 2-mercaptonicotinic acid, abbreviated to Ag─NCs hereafter) containing uncoordinated carboxyl groups with water-soluble fullerene derivatives modified with multiple hydroxyl groups (fullerenols, C─OH), the π-electron delocalization is expanded owing to non-covalent hydrogen bonding effect between Ag6─NCs and C─OH, which provides a feasible basis for realizing the NLO response.
View Article and Find Full Text PDFJ Clin Med
January 2025
Department of Sciences, Section of Biomedical Sciences and Technologies, Roma Tre University, Viale Marconi 446, 00146 Rome, Italy.
: Diabetes is a well-recognised factor inducing a plethora of corneal alterations ranging from dry eye to reduced corneal sensibility, epithelial defects, and reduced cicatrisation. This cohort study aimed to assess the efficacy of a novel ophthalmic solution combining cross-linked hyaluronic acid (CHA), chondroitin sulfate (CS), and inositol (INS) in managing diabetes-induced corneal alterations. Specifically, it evaluated the solution's impact on the tear breakup time (TBUT), the ocular surface disease index (OSDI), and corneal sensitivity after three months of treatment.
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