The impact of small-scale land cover and groundwater interactions on base flow solute and nutrient export in a small agricultural stream.

Central Kentucky could be considered a critical source area of nutrients in water ways because of low permeability soils, fast groundwater flow through bedrock fractures, and pervasive agriculture and development. Of particular concern is rising development in rural areas, which creates mixed land cover (MLC) watersheds, i.e., watersheds with development, agriculture, and other land cover types. MLC watersheds add complexity to spatial and temporal releases of dissolved constituents, leading to less predictable water quality patterns. The goal of this research was to examine the export of dissolved substances from a small, upland MLC catchment in central Kentucky with a focus on how the interaction between discharges from developed agricultural land cover and groundwater influence base flow water quality. Our approach was to spatially sample a representative catchment monthly over 1 year, characterize the major dissolved constituents, and evaluate catchment processes with statistical analyses and Piper diagrams. Principal component analysis, factor analysis, and Piper diagrams indicate base flow was composed of groundwater influenced by two different host rocks and an outfall draining a developed region. Base flow nutrient export was dominated by mixing nitrate-sulfate rich groundwater with ammonium-phosphate-chloride rich outfall drainage. High nitrate groundwater dominated nitrogen export in the winter, whereas high ammonium outfall drainage dominated summer export. Spatial analysis revealed that ~ 10% of the basin may have similar land cover and hydrologic processes, suggesting that MLC catchments are small but collectively significant nitrogen sources to river networks due to development and agriculturally impacted groundwater.