Valorization of plastics and paper mill sludge into carbon composite and its catalytic performance for acarbon material consisted of the multi-layerzo dye oxidation.

In this work, polyvinyl chloride (PVC) and paper mill sludge (PMS) were co-pyrolyzed under two environments of N and CO. The pyrolysis process was assessed by conducting thermogravimetric analysis (TGA) and monitoring the evolution of gaseous products. The resulting solid composites were characterized using XRD, XPS, BET, and Raman analyzers, and their ability to catalytically activate persulfate (SO) was tested by conducting methyl orange (MO) degradation experiments. Co-pyrolysis of PVC and PMS at the same mass ratio (1:1) in CO resulted in the highest production of H and CO (0.36 mol % H at 480 °C & 1.53 mol % CO at 700 °C). The characterization results revealed that the composite consisted of FeO, highly graphitic carbon, and mesoporous structure. In MO oxidation experiments, the co-pyrolyzed composite actively generated OH and SO by activating SO to achieve complete removal of 5 mg L of MO during 100 min at acidic-neutral pH condition. The composite was also able to complete 3 successive cycles of MO oxidation without deactivation. Consequently, the feasibility of achieving the simultaneous production of energy resources and catalyst via industrial wastes utilization in pyrolytic process was demonstrated.