Carbon quantum dots-TiO nanocomposite as an efficient photocatalyst for the photodegradation of aromatic ring-containing mixed VOCs: An experimental and DFT studies of adsorption and electronic structure of the interface.

In this work, we have developed and optimized TiO nanoparticles decorated with carbon quantum dots to examine its potential use in the photocatalytic oxidation of aromatic ring containing gas-phase mixed volatile organic compounds, e.g., benzene, toluene, and p-xylene. Carbon quantum dots decorated TiO demonstrated good photodegradation efficiency in contrast to pure TiO under UV-vis light illumination. For example, with 0.5 wt% carbon quantum dots decorated on TiO, 64 % of the mixed volatile organic compounds were photodegraded, while pure TiO only exhibited 44 % of the photodegradation efficiency. Also, the carbon quantum dots (0.5 wt%)/TiO nanocomposite demonstrated considerable photocatalytic activity within the visible region. On the other hand, pure TiO remained inactive within the visible region. The density functional theory study of the carbon quantum dots/TiO interface revealed that C 2p states of carbon quantum dots incorporated new energy states around the Fermi level near the lowest conduction band. This might be accountable for the improved charge separation process and better conductivity of the photogenerated electrons. The improved photocatalytic performance of the carbon quantum dots/TiO nanocomposites can be attributed to good light harvesting within the UV-vis region, charge separation, and adsorption capability.