A series of POM-based all-inorganic open frameworks, H[LnW(μ-O)(μ-O)(HO)](SiWO)·60HO (1-Ln, Ln = La, Pr and Nd), have been fabricated and structurally characterized for the first time. The unique architectures are constructed from nanoscale four-shell Ln@W@Ln@(SiW) clusters. Additionally, the porous nature of the frameworks has also been investigated.
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| http://dx.doi.org/10.1039/d0cc04070c | DOI Listing |
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