We investigated the selective excitation of localized surface plasmons by structured light. We derive selection rules using group theory and propose a fitting integral to quantify the contribution of the eigenmodes to the absorption spectra. Based on the result we investigate three nano oligomers of different symmetry (trimer, quadrumer, and hexamer) in detail using finite-difference time-domain simulations. We show that by controlling the incident light polarization and phase pattern we are able to control the absorption and scattering spectra. Additionally, we demonstrate that the fitting between the incident light and the oligomer modes may favor a number of modes to oscillate. Dark modes produce strong changes in the absorption spectrum and bright modes in the scattering spectrum. The experimental precision (axial shift error) may be on the same order as the oligomer diameter making the orbital angular momentum selection rules robust enough for experimental observation.
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http://dx.doi.org/10.1364/OE.399225 | DOI Listing |
Sci Rep
January 2025
Department of Chemistry, School of Advanced Sciences, VIT-AP University, Amaravati, 522237, India.
CQHC, a novel colorimetric fluorescent sensor, developed for the selective sensing of ions and well characterised, including SC-XRD. It demonstrated selective sensing for Co, Zn, Hg and F using absorbance titration at 420 nm, 446 nm and the binding constants estimated follows the order F > Co > Hg > Zn. On light of this, molecular logic gate was built for CQHC's selective multi-ion detection.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
College of Food Science and Light Industry, Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China; State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China. Electronic address:
In this study, a cyanine skeleton fluorescent parent core was designed based on the intramolecular charge transfer (ICT) principle, and 2, 4-dinitrofluorobenzene (DNFB) was used as the specific recognition site for phenylthiophene (PhSH). The probe showed a fluorescence transition from colorless to red under 410 nm excitation, which had the characteristics of fast response, high selectivity, low detection limit (55 nM), and the fluorescence intensity showed a positive linear correlation with PhSH concentration in the range of 0-100 μM (R = 0.9921).
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Key Laboratory of Advanced Light Conversion Materials and Biophotonics, School of Chemistry and Life Resources, Renmin University of China, Beijing 100872, P. R. China.
Chlorophyll (Chl) is the most abundant light-harvesting pigment of oxygenic photosynthetic organisms; however, the Q-band energetics and relaxation dynamics remain unclear. In this work, we have applied femtosecond time-resolved (-TA) absorption spectroscopy in 430-1,700 nm to Chls and in diluted pyridine solutions under selective optical excitation within their Q-bands. The results revealed distinct near-infrared absorption features of the B ← Q and B ← Q transitions in 930-1,700 nm, which together with the steady-state absorption in 400-700 nm unveiled the Q-state energy that lies 1,000 ± 400 and 600 ± 400 cm above the Q-state for Chls and , respectively.
View Article and Find Full Text PDFBiological memory networks are thought to store information by experience-dependent changes in the synaptic connectivity between assemblies of neurons. Recent models suggest that these assemblies contain both excitatory and inhibitory neurons (E/I assemblies), resulting in co-tuning and precise balance of excitation and inhibition. To understand computational consequences of E/I assemblies under biologically realistic constraints we built a spiking network model based on experimental data from telencephalic area Dp of adult zebrafish, a precisely balanced recurrent network homologous to piriform cortex.
View Article and Find Full Text PDFOrg Biomol Chem
January 2025
Department of Pharmacy, The Affiliated Cancer Hospital of Zhengzhou University & Henan Cancer Hospital, Zhengzhou 450008, China.
detection of hypochlorous acid (HOCl) is critical for understanding its complex physiological and pathological roles. Fluorescent probes, known for their sensitivity and selectivity, are the preferred approach for such detections. Anthracene carboxyimide, an analog of naphthalimide, offers extended excitation and emission wavelengths, making it an excellent candidate for developing new fluorescent probes that address the limitations of naphthalimide.
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