Bioaccessibility-based extraction tools, such as single-point Tenax extractions (SPTEs), provide cost-effective and accurate estimates of bioaccumulation and toxicity of hydrophobic organic contaminants during environmental sampling. Use of SPTEs as a screening tool in risk assessment is hindered by the requirement for normalization of extractable concentrations for organic carbon (OC). Normalizing SPTE concentrations for the volume of Tenax used during the extraction could improve the applicability of this methodology by removing the system dependence when applying SPTE concentrations to estimates of bioaccumulation. The objective of this study was to examine the utility of Tenax phase volume normalization in place of OC normalization when using SPTEs to estimate bioaccumulation. No significant differences were observed between the slope of regression lines generated between SPTE concentrations normalized for either Tenax phase volume or OC (p = 0.410), but slight improvement of the regression was noted when using phase volume normalization (R = 0.829) compared to OC normalization (R = 0.740). Replacing OC normalization with phase volume normalization in use of SPTEs more accurately represents the partition of the chemical to the Tenax during the SPTE, improves estimates of bioaccumulation, and expands the use of SPTEs as a rapid assessment tool for determining bioaccumulation during screening of contaminated environments.
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http://dx.doi.org/10.1016/j.chemosphere.2020.127811 | DOI Listing |
Anal Chem
January 2025
Department of Life Technologies/Biotechnology, Faculty of Technology, University of Turku, Kiinamyllynkatu 10, 20520 Turku, Finland.
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View Article and Find Full Text PDFSci Rep
January 2025
Centre for Advanced 2D Materials, National University of Singapore, Singapore, 117546, Singapore.
Kaolinite is a single 2D layer of kaolin or metakaolin (MK), common clays that can be characterized as layered 3D materials. We show that because of its chemical composition, kaolinite can be converted into an amorphous 3D material by chemical means. This dimensional transformation is possible due to the large surface to volume ratio and chemical reactivity of kaolinite.
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January 2025
Department of Urology, Sun Yat-sen University Cancer Center, Guangzhou, P. R. China; State Key Laboratory of Oncology in Southern China; Collaborative Innovation Center for Cancer Medicine, Guangzhou, China; State Key Laboratory of Oncology in Southern China, Guangzhou, P. R. China. Electronic address:
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View Article and Find Full Text PDFNeuroimage
January 2025
Department of Medical Imaging, the First Affiliated Hospital of Xi'an Jiaotong University, Xi'an, Shaanxi Province, China. Electronic address:
Background: Fatigue is often accompanied by comorbid sleep disturbance and psychiatric distress following the COVID-19 infection. However, identifying individuals at risk for developing post-COVID fatigue remains challenging. This study aimed to identify the neurobiological markers underlying fatigue susceptibility and further investigate their effect on COVID-19-related neuropsychiatric symptoms.
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Chemistry Department, Faculty of Science, Damietta University, Damietta 34517, Egypt. Electronic address:
The VCo-LDH/CS hydrogel beads were created by combining VCo-layered double hydroxide (VCo-LDH) and chitosan (CS) using a cross-linking process with epichlorohydrin. These beads were specifically designed to remove tetracycline (TTC). To characterize the VCo-LDH/CS hydrogel beads, several analytical techniques were used, with PXRD, XPS, FESEM, EDX, and FT-IR.
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