In this study, a tunable bifunctional polarization-independent metamaterial device based on Dirac semimetal films (DSFs) and vanadium dioxide () is investigated. At the insulator state, a polarization-independent electromagnetically induced reflectance effect can be achieved via destructive interference between bright and dark modes. When transitions to a metallic state, the proposed device behaves as a dual-band polarization-independent absorber with 99.9% and 94.5% absorptance at 9.06 and 10.9 THz, respectively, and is insensitive over a wide range of incidence angles. In both cases, refractive index sensing is achieved, and the response can be dynamically tuned by changing the Fermi energy of the DSF.
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http://dx.doi.org/10.1364/JOSAA.397273 | DOI Listing |
Small Methods
January 2025
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 401331, China.
Bilayer graphene ribbons (GRs) hold great promise for the fabrication of next-generation nanodevices, thanks to unparalleled electronic properties, especially the tunable bandgap in association with twist angle, ribbon width, edge structure, and interlayer coupling. A common challenge in manufacturing bilayer GRs via templated chemical vapor deposition (CVD) approach is uncontrollable dewetting of micro- and nano-scaled patterned metal substrates. Herein, a confined CVD synthetic strategy of bilayer GR arrays is proposed, by utilizing the bifunctional Ni as a buffered adhesion layer to regulate the anisotropic dewetting of metal film in the V-groove and as a carbon-dissolution regulated metal to initiate the bilayer nucleation.
View Article and Find Full Text PDFSmall Methods
January 2025
Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, School of Resources, Environment and Materials, Guangxi University, Nanning, Guangxi, 530004, China.
Urea-assisted water splitting is a promising energy-saving hydrogen (H) production technology. However, its practical application is hindered by the lack of high-performance bifunctional catalysts for urea oxidation reaction (UOR) and hydrogen evolution reaction (HER). Herein, a heterostructured catalyst comprising highly active NiSe and NiSe, along with a conductive graphene-coated nickel foam skeleton (NiSe-NiSe/GNF) is reported.
View Article and Find Full Text PDFJ Mater Chem B
January 2025
Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany.
Hydrogels based on supramolecular assemblies offer attractive features for biomedical applications including injectability or versatile combinations of various building blocks. We here investigate a system combining benzenetrispeptides (BTP), which forms supramolecular fibers, with polymer polyethylene oxide (PEO) forming a dense hydrophilic shell around the fibers. Hydrogels are created through the addition of a bifunctional crosslinker (CL).
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Laboratory of Polymeric and Composite Materials, University of Mons, Place du Parc 23, 7000, Mons-, Belgium.
This study introduces a novel one-pot strategy for the chemical valorization of poly(lactic acid) (PLA), coupling its base-catalyzed depolymerization with the ring-opening polymerization (ROP) of trimethylene carbonate (TMC). The process exploits an eutectic mixture of lactide (LA) and TMC, which lowers the thermal input required for PLA degradation. Using potassium aryloxide (KOAr) as a bifunctional catalyst, the PLA is first quickly hydrolyzed into oligomers or lactic acid, which subsequently initiate the slower polymerization of TMC.
View Article and Find Full Text PDFAdv Mater
December 2024
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning, 116023, P. R. China.
Constructing built-in electric field (BIEF) in heterojunction catalyst is an effective way to optimize adsorption/desorption of reaction intermediates, while its precise tailor to achieve efficient bifunctional electrocatalysis remains great challenge. Herein, the hollow Mo/MoS nanoreactors with tunable BIEFs are elaborately prepared to simultaneously promote hydrogen evolution reaction (HER) and urea oxidation reaction (UOR) for sustainable hydrogen production. The BIEF induced by sulfur vacancies can be modulated from 0.
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