A new, very short-lived neutron-deficient isotope ^{222}Np was produced in the complete-fusion reaction ^{187}Re(^{40}Ar,5n)^{222}Np, and observed at the gas-filled recoil separator SHANS. The new isotope ^{222}Np was identified by employing a recoil-α correlation measurement, and six α-decay chains were established for it. The decay properties of ^{222}Np with E_{α}=10016(33) keV and T_{1/2}=380_{-110}^{+260} ns were determined experimentally. The α-decay systematics of Np isotopes is improved by adding the new data for ^{222}Np, which validates the N=126 shell effect in Np isotopes. The evolution of the N=126 shell closure is discussed in the neutron-deficient nuclei up to Np within the framework of α-decay reduced width.
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http://dx.doi.org/10.1103/PhysRevLett.125.032502 | DOI Listing |
J Environ Radioact
January 2023
Analytical Chemistry and Control Department, Hot Labs and Waste Management Center, Egyptian Atomic Energy Authority, Post Office Code 13759, Cairo, Egypt.
Large amounts of TENORM waste (produced water, scale, and sludge) are created in oilfields around the world, presenting radiological risks to employees, the public, and the environment since activity concentrations of radioactive substances were above the exemption levels accredited by several authorities. Using the activity concentration of the radium-isotopes (Ra and Ra) in the waste, we determined the 'fingerprint' as a radiochemical signature and some relevant 'radiological hazard parameters' in this review. The majority of the reported residues take the form of radio-contaminated (produced water, scale, and sludge) generated in Egypt's oilfields or elsewhere include radium isotope activity concentrations (Ra) that exceed the international exemption limit.
View Article and Find Full Text PDFPhys Rev Lett
July 2020
CAS Key Laboratory of High Precision Nuclear Spectroscopy, Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
A new, very short-lived neutron-deficient isotope ^{222}Np was produced in the complete-fusion reaction ^{187}Re(^{40}Ar,5n)^{222}Np, and observed at the gas-filled recoil separator SHANS. The new isotope ^{222}Np was identified by employing a recoil-α correlation measurement, and six α-decay chains were established for it. The decay properties of ^{222}Np with E_{α}=10016(33) keV and T_{1/2}=380_{-110}^{+260} ns were determined experimentally.
View Article and Find Full Text PDFJ Am Chem Soc
November 2009
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA.
The catalytic mechanism of the hydrogen-mediated coupling of acetylene to carbonyl compounds and imines has been examined using three techniques: (a) ESI-MS and ESI-CAD-MS analyses, (b) computational modeling, and (c) experiments wherein putative reactive intermediates are diverted to alternate reaction products. ESI-MS analysis of reaction mixtures from the hydrogen-mediated reductive coupling of acetylene to alpha-ketoesters or N-benzenesulfonyl aldimines corroborate a catalytic mechanism involving C horizontal lineX (X = O, NSO(2)Ph) insertion into a cationic rhodacyclopentadiene obtained by way of acetylene oxidative dimerization with subsequent Brønsted acid cocatalyzed hydrogenolysis of the resulting oxa- or azarhodacycloheptadiene. Hydrogenation of 1,6-diynes in the presence of alpha-ketoesters provides analogous coupling products.
View Article and Find Full Text PDFJ Environ Radioact
March 2007
ECOMatters Inc., 24 Aberdeen Avenue, P.O. Box 430, Pinawa, Manitoba, Canada R0E 1L0.
There is a continual supply of new experimental data that are relevant to the assessment of the potential impacts of nuclear fuel waste disposal. In the biosphere, the traditional assessment models are data intensive, and values are needed for several thousand parameters. This is augmented further when measures of central tendency, statistical dispersion, correlations and truncations are required for each parameter to allow probabilistic risk assessment.
View Article and Find Full Text PDFAm J Physiol Heart Circ Physiol
March 2001
Department of Pharmacology and Toxicology, Medical College of Wisconsin, Milwaukee, Wisconsin 53226, USA.
Endothelium-derived hyperpolarizing factor (EDHF) is released in response to agonists such as ACh and bradykinin and regulates vascular smooth muscle tone. Several studies have indicated that ouabain blocks agonist-induced, endothelium-dependent hyperpolarization of smooth muscle. We have demonstrated that epoxyeicosatrienoic acids (EETs), cytochrome P-450 metabolites of arachidonic acid, function as EDHFs.
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